Reverse osmosis systems treating hard water must handle mineral concentrations of 120-180 mg/L calcium carbonate, with some municipal sources exceeding 200 mg/L. These dissolved solids not only impact membrane performance but lead to scaling that reduces system efficiency by 10-15% within months of operation and can cut membrane lifespans in half.

The fundamental challenge lies in maintaining consistent permeate quality and flow rates while managing mineral scaling and membrane fouling in high-hardness conditions.

This page brings together solutions from recent research—including two-stage systems with interstage pressure exchange, nanofiltration pretreatment approaches, and composite membranes with enhanced anti-fouling properties. These and other approaches focus on extending membrane life and reducing maintenance requirements in hard water applications.

1. Reverse Osmosis Pretreatment System with Chemical Crystallization, Solid-Liquid Separation, Filtration, and Polyceramic Ultrafiltration Components

XIAN LOGEN TECH DEVELOPMENT CO LTD, XIAN LOGEN TECHNOLOGY DEVELOPMENT CO LTD, 2023

A simplified and compact reverse osmosis pretreatment system for high hardness water that reduces hardness levels to meet reverse osmosis requirements. The system consists of four main components: chemical crystallization granulation, solid-liquid separation, filtration, and polyceramic ultrafiltration. This allows effective removal of hardness, particularly carbonate, without the complexities and issues of traditional lime treatment or double-alkali softening. It provides a simpler, more automated, space-saving, and environmentally friendly option for high hardness water reverse osmosis pretreatment.

2. Method for Reverse Osmosis Desalination with Pre-Treatment Softening Using Caustic Soda

PERVOV ALEKSEJ GERMANOVICH, 2021

A method to improve efficiency and reliability of reverse osmosis desalination of saline water by reducing concentrate consumption and utilizing it. The method involves softening the saline water before desalination using a small amount of caustic soda. This reduces the amount of calcium and magnesium ions in the water that can foul the reverse osmosis membranes. This allows using a lower operating pressure, reducing the concentrate flow and making it easier to utilize. The softened water is then desalinated by reverse osmosis.

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3. Composite Reverse Osmosis Membranes with Acacia Gum-Enhanced Interfacial Polymerization Structure

Qatar Foundation, 2021

Composite RO membranes with improved properties for reverse osmosis desalination and purification of water. The membranes are made by interfacial polymerization using acacia gum as an additive. The acacia gum increases pore size, hydrophilicity, and surface charge and reduces roughness compared to pure polyamide membranes. This leads to higher membrane flux and reduced fouling while maintaining salt rejection. The composite membranes show improved performance and stability in filtration tests with seawater compared to commercial membranes.

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4. Multi-Tank Reverse Osmosis System with Sequential Evaporation and Condensation Stages

ZHEJIANG LVCHUANG ENVIRONMENTAL PROTECTION TECH CO LTD, ZHEJIANG LVCHUANG ENVIRONMENTAL PROTECTION TECHNOLOGY CO LTD, 2020

A reverse osmosis water filtration system to efficiently remove hardness from water. The system uses three tanks: a boiling tank, a condensation tank, and a reverse osmosis filtration tank. Boiling the water in the first tank to evaporate hardness-causing minerals, then condensing the vapor in the second tank to separate the purified water. The condensed water is fed to the reverse osmosis filter in the third tank to remove any remaining impurities. This multi-stage process provides a more effective hardness removal compared to directly filtering hard water with a reverse osmosis membrane.

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5. Direct Drinking Water System with Compressed Carbon, Media, Softening, Reverse Osmosis, and UV Sterilization Stages

HANGZHOU WEILAIYILAI TECH CO LTD, HANGZHOU WEILAIYILAI TECHNOLOGY CO LTD, 2020

Direct drinking water system with multi-stage filtration and purification to produce high-quality, healthy drinking water. The system includes stages of compressed carbon filter, media filter, water softening, reverse osmosis (RO) membrane, and UV sterilization. This multi-stage filtration removes impurities, softens water, removes contaminants, and further purifies through RO and UV to provide direct drinking water that meets World Health Organization standards for healthy water.

6. Brackish Water Desalination System with Staged Chemical Dosing and Mixing for Hardness Reduction

DALIAN WEIQING ENV ENGINEERING CO LTD, DALIAN WEIQING ENVIRONMENTAL ENGINEERING CO LTD, 2019

A high-hardness brackish water desalination system that can effectively treat water with high hardness levels without blocking reverse osmosis membranes. The system uses a staged chemical dosing and mixing process to soften the water before reverse osmosis. The process involves pumping high-hardness brackish water into a regulating tank, then pumping it to a reaction tank where NaOH and Na2CO3 are dosed. A flocculant is also dosed. The reaction tank overflow goes to a circulating tank. This softened water is then fed to reverse osmosis for desalination. The stages of chemical dosing and mixing help remove the hardness components before reverse osmosis, preventing membrane fouling.

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7. Water Purifier with Multi-Stage Filtration Including High Molecular Polymer Composite and Ultrafiltration Pre-Treatment

SHENZHEN ANGEL DRINKING WATER IND GROUP CORP, SHENZHEN ANGEL DRINKING WATER INDUSTRY GROUP CORP, 2019

A water purifier with improved water purification rate and reduced scaling risk, particularly for areas with hard water. The purifier has multiple stages of filtration. Before reverse osmosis, the natural water is pretreated with a high molecular polymer composite filter to remove sediment, chlorine, and calcium/magnesium ions. This reduces scaling on the RO membrane by preventing calcium/magnesium crystallization. An ultrafiltration stage further traps non-directional agglomerated ions. This pre-filtration extends the life of the RO membrane in high hardness water with high recovery rates.

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8. Reverse Osmosis Concentrate Treatment Device with Nanofiltration and Multi-Stage Membrane System for Calcium and Magnesium Removal

Shanghai Tongjie Environmental Protection Technology Co., Ltd., 2019

Reverse osmosis concentrated water treatment device that reduces hardness without lime or soda ash. The device uses nanofiltration followed by multiple stages of Dow membranes to remove calcium and magnesium from reverse osmosis concentrate. The nanofiltration removes some impurities before the Dow membranes. The Dow membranes have multiple stages with intermediate pumps and recirculation to incrementally reduce impurities. This avoids using lime or soda ash for precipitation and has lower cost, smaller footprint, and higher recycling rate compared to traditional lime softening.

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9. Multi-Stage Water Treatment System with Inclined Bottom Softening Tank and Integrated Sludge Discharge Mechanism

Beijing Enterprises Group Co., Ltd., 2019

A softened water treatment and recovery system for high hardness water sources that reduces scale buildup and prolongs membrane life. The system uses a multi-stage filter configuration with sand, activated carbon, softening, precision filtration, and reverse osmosis. A booster pump provides pressure for the filters. The softening tank has multiple stages and inclined bottoms to prevent scaling. The system also has sludge discharge valves, recovery tank, and a feed port for chemicals.

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10. Membrane-Based Water Treatment System with Sequential Ultrafiltration and Nanofiltration Units

BL TECHNOLOGIES INC, 2018

A water treatment system that replaces traditional ion exchange water softeners using a combination of ultrafiltration (UF) and nanofiltration (NF) membranes. The system filters and softens water without adding salt or discharging chloride-rich waste. The UF unit removes particles, and the NF unit removes hardness ions like calcium and magnesium. The system has the UF unit upstream of the NF unit, with permeate from the UF fed to the NF. NF permeate is used to flush and backwash the UF and NF membranes. This allows continuous treatment without salt, unlike ion exchange.

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11. Water Treatment System with Pre-Filtration Sub-Membrane Device for Reverse Osmosis Membranes

MITSUBISHI HEAVY INDUSTRIES, LTD., 2017

A water treatment device and method to reduce fouling and scaling in reverse osmosis membranes, enabling longer operation and reduced maintenance. The method involves using a sub-reverse osmosis membrane device with a lower operating pressure to filter the feed water before it enters the main reverse osmosis membranes. This traps foreign materials that can deposit in the main membranes. The sub-membrane device only filters, not desalinates, to limit fouling. Backwashing can be done by reversing feed flow through the sub-membrane. The method involves switching between normal operation and backwashing.

12. Desalination System Using Municipal Water Pressure and Venturi-Induced Vacuum for Reverse Osmosis

Uri Rapoport, 2016

Utilizing municipal water supply pressure to desalinate water without external energy sources using a venturi effect. The method involves connecting a pipe to a municipal water supply, adding a venturi arrangement with two nozzles and a branch, and using the vacuum created by the venturi effect to draw in contaminated water from one side. The vacuum suction is used to force the contaminated water through a reverse osmosis membrane on the other side to desalinate it. This allows desalination using only the municipal water supply pressure without any external energy sources.

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Because of its high mineral content, hard water can be harmful to drink and cause other problems like scaling, dry skin, and trouble cleaning filters. Researchers have overcome this challenge by using reverse osmosis desalination to soften the hard water.

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