Concrete Formulations for Enhanced Freeze-Thaw Resistance
Concrete deterioration due to freeze-thaw cycles remains a critical challenge in cold climates, where temperatures regularly oscillate around the freezing point. Field measurements show that a single winter season can subject concrete to 50-100 freeze-thaw cycles, with internal pressures exceeding 29 MPa during ice formation, leading to progressive microstructural damage and reduced service life.
The fundamental challenge lies in developing concrete mixtures that maintain structural integrity while managing internal water movement and ice crystal formation through hundreds of freeze-thaw cycles.
This page brings together solutions from recent research—including nano-modified composites with phase change materials, specialized antifreeze agents incorporating nanocellulose crystals, self-healing gels with biological antifreeze proteins, and innovative supplementary cementitious materials. These and other approaches focus on practical implementation strategies that enhance freeze-thaw durability while maintaining constructability and cost-effectiveness.
1. Concrete Composite with Specialized Additive for Enhanced Freeze-Thaw Resistance
ZHEJIANG YOHO NEW MATERIAL TECHNOLOGY CO LTD, 2025
Freeze-thaw resistant concrete comprising a composite of cement, aggregate, sand, fly ash, additive A, water-reducing agent, dispersant, defoamer, modified fiber, and water. The composite also contains a specific additive A that enhances the concrete's resistance to freeze-thaw cycles. The additive A is prepared by a specialized process that creates a unique combination of properties that provide superior freeze-thaw resistance compared to conventional additives.
2. Concrete Preparation Method with Additives, Microspheres, Antifreeze, and Silane Coupling Agents
NORTHWEST POWER CONSTRUCTION ENG CO LTD OF CHINA ENERGY CONSTRUCTION GROUP, 2024
Frost-resistant concrete preparation method that enhances freeze-thaw durability through a novel combination of additives and microspheres. The method involves preparing a primary mixture of cement, aggregate, and admixtures, followed by the incorporation of an antifreeze agent and a silane coupling agent. The mixture is then mixed with microspheres that expand upon heating, creating a frost-resistant concrete with enhanced freeze-thaw resistance.
3. Concrete Composition with Dolomite-Based Slag and Nano-SiO2 Integrating Solid Phase Change Material
UNIV SOUTHEAST, 2024
Full-hole slag phase change frost-resistant concrete comprising a matrix of Portland cement, dolomite-based cave slag powder, dolomite-based cave slag sand, nano-SiO2, solid phase change material, and water. The concrete combines the mechanical properties of the matrix with the frost-resistance properties of the phase change material, achieving enhanced antifreeze performance while maintaining structural integrity.
4. Ultra-High Performance Concrete with Composite Antifreeze Agent Incorporating Nanocellulose Crystals
UNIV CHONGQING JIAOTONG, 2024
Ultra-high performance concrete for extreme temperature environments featuring enhanced durability and early strength. The concrete combines traditional cement with advanced additives, including a composite antifreeze agent that prevents water expansion during freezing, while maintaining optimal hydration rates. This combination enables rapid development of strength in both warm and cold temperature environments, with improved resistance to frost heave and microcracking. The antifreeze agent, comprising nanocellulose crystals and other synergistic components, forms a protective barrier against water expansion during freezing, while promoting early hydration and densification.
5. Concrete Composition with Supplementary Cementitious Materials and Additives for Enhanced Freeze-Thaw Durability
DR.KUSUMA SUNDARA KUMAR PROFESSOR& HOD RAMACHANDRA COLLEGE OF ENGINEERING, 2024
Enhancing freeze-thaw durability of concrete through the incorporation of supplementary cementitious materials (SCMs) and environmentally friendly additives. The formulation combines SCMs like fly ash, silica fume, and slag with innovative additives like nano-silica, fibers, and hydrophobic agents to create a concrete matrix that resists freeze-thaw cycles. The SCMs improve microstructure and reduce porosity, while the additives enhance hydration, reduce water content, and increase density. The hydrophobic agents further prevent water absorption, significantly reducing freeze-thaw damage. This advanced formulation offers improved durability in cold climates and reduces carbon footprint compared to conventional methods.
6. Phase Change Concrete Incorporating Nano-Polymer Emulsion and Inorganic Nano-Materials
MIANZHU ZHUCHENG CONCRETE CO LTD, 2024
Environmentally friendly phase change concrete that replaces traditional phase change materials with sustainable inorganic components. The concrete combines nano-polymer emulsion with inorganic nano-inorganic materials, such as nano-silica and nano-calcium carbonate, to create a phase change material that can absorb and release heat through freeze-thaw cycles. The material is formulated with a polymer emulsion, desulfurized gypsum, inorganic fibers, and nano-inorganic materials, which are combined with water, cement, and quartz sand to create a prefabricated phase change concrete.
7. Recycled Concrete with Natural Aggregates and Water-Absorbing Agent for Enhanced Freeze-Thaw Resistance
CHONGDE BUILDING MATERIALS GROUP CO LTD, 2024
Freeze-thaw resistant recycled concrete that combines natural aggregates with a unique water-absorbing agent to enhance its durability. The recycled concrete incorporates natural aggregates, cement, sand, and a specialized water-absorbing agent that prevents water absorption and promotes hydration in cracks. This approach significantly improves the concrete's resistance to freeze-thaw cycles compared to conventional recycled concrete.
8. Concrete Matrix with Fish Antifreeze Protein-Infused Self-Healing Gel
BEIJING ZEHUA ROAD AND BRIDGE ENGINEERING CO LTD, 北京泽华路桥工程有限公司, 2023
High-strength anti-freeze concrete with improved frost resistance and self-healing properties. The concrete contains a specialized self-healing gel that incorporates a fish antifreeze protein solution, which is dissolved in ethyl acetate. The gel is incorporated into the concrete matrix during preparation, where it forms a network of dissolved protein and lipid molecules that provide enhanced frost resistance. The self-healing gel also exhibits improved durability against repeated freezing and thawing cycles. The concrete achieves enhanced frost resistance and compressive strength compared to conventional anti-freeze treatments, while maintaining superior self-healing capabilities.
9. Concrete Mixture Incorporating Acid Water Reducing Agent and Rubber Particles for Freeze-Thaw Resistance
SHENZHEN BAOJINHUA CONCRETE CO LTD, 2023
A method for enhancing freeze-thaw resistance in concrete through the addition of an acid water reducing agent. The method involves combining an acid water reducing agent with a controlled proportion of rubber particles in the concrete mixture. The acid water reducing agent, typically polyvinyl acid (PVA), helps to neutralize acidic water that can cause damage to the concrete during freeze-thaw cycles. The proportion of rubber particles can be adjusted to achieve the desired level of freeze-thaw resistance while maintaining the structural integrity of the concrete.
10. Concrete Preparation Method with Specialized Additives for Enhanced Thermal Stability and Durability
HENAN XINXING NEW MATERIAL TECH CO LTD, 2023
A method for improving the frost resistance of concrete by incorporating specialized additives that enhance its thermal stability and durability. The method involves preparing concrete by combining cement, fly ash, sand, fine stone, water, water-reducing agent, air-entraining agent, and a proprietary additive. The additive combines with the cement to form a composite material that enhances the concrete's thermal resistance and durability characteristics, particularly in freeze-thaw environments.
11. Concrete Composition with Reinforced Recycled Aggregate and Air-Entraining Agents for Enhanced Freeze-Thaw Resistance
JINAN SHENGHUA CONCRETE CO LTD, 2023
Antifreeze concrete with enhanced freeze-thaw resistance through the use of reinforced recycled aggregate. The concrete combines a specially prepared recycled aggregate with natural stone and cement, incorporating air-entraining agents to enhance foam formation. The aggregate is processed to achieve specific particle size ratios, with the 15-20mm and 9.5-15mm sizes forming a 1:2 ratio. This combination provides improved freeze-thaw durability compared to conventional recycled aggregate concrete.
12. Concrete Composition with Mineral Admixture, PV-PEG, and Nano Carbon Black for Frost Resistance
CHINA CONSTRUCTION EIGHTH ENGINEERING DIVISION TESTING TECH CO LTD, 2022
Frost-resistant plateau concrete with enhanced durability in high-altitude regions. The concrete combines a base material with mineral admixture, polyvinyl alcohol-polypeptide-polyethylene glycol (PV-PEG), and nano carbon black to create a frost-resistant concrete. The PV-PEG and nano carbon black work synergistically to prevent water absorption and ice formation, while the PV-PEG enhances the concrete's thermal resistance. The concrete achieves freeze resistance at elevated temperatures through its unique combination of properties.
13. Permeable Concrete Incorporating Ultrafine Silica and Nano-Silicon Carbide for Enhanced Freeze-Thaw Resistance
GUANGZHOU CHANGYUN READY MIXED CONCRETE CO LTD, Guangzhou Changyun Ready-Mix Concrete Co., Ltd., 2022
Permeable concrete for green infrastructure that enhances durability and performance in cold climates. The innovative concrete combines ultrafine silica with nano-silicon carbide to create a superior freeze-thaw resistance profile compared to traditional permeable concrete. This hybrid material incorporates ultrafine silica to fill the pores, while nano-silicon carbide reinforces the structure against thermal stress. The combination provides enhanced freeze-thaw resistance, improved durability, and enhanced performance in cold climates.
14. Composite Wave Retaining Wall Material with Temperature-Sensitive Hydrogel and Polyvinyl Alcohol Fibers
CHINA HARBOUR ENG CO LTD, 2022
Wave retaining wall material comprising cement, basalt, sand, nanocomposite temperature-sensitive hydrogel, polyvinyl alcohol fibers, water, slag powder, and swelling agent. The material incorporates a temperature-sensitive hydrogel that modifies the concrete's thermal expansion properties and mechanical properties, enhancing its resistance to freeze-thaw damage and abrasion. The hydrogel is prepared through a modified graphene oxide aqueous solution process that incorporates cyclodextrin and N-isopropylacrylamide. This innovative material provides superior frost resistance and wear resistance while maintaining optimal workability and durability for wave retaining wall applications.
15. Concrete Preparation Method Incorporating Graphene and Air-Entraining Agents with Powder Blend of Portland Cement, Fly Ash, Granite Powder, and Silica Fume
XIAOYUN LIN, 2022
A method for preparing concrete with enhanced freeze-thaw resistance through the incorporation of graphene and air-entraining agents. The preparation involves mixing a powder blend containing Portland cement, fly ash, granite powder, and silica fume with an air-entraining agent, followed by the addition of water. The mixture is then stirred to create a uniform paste, with additional graphene sheets added to enhance the concrete's thermal shock resistance. The resulting composite concrete exhibits superior freeze-thaw durability compared to conventional concrete, with a significant increase in resistance to thermal cracking and damage.
16. Concrete Composition with Additive Forming Protective Layer to Inhibit Freezing-Induced Expansion
XIAN XINYIDA BUILDING PRODUCTS CO LTD, 2021
Antifreeze concrete for cold climates that prevents concrete expansion and damage due to freezing temperatures. The concrete formulation incorporates a specialized additive that prevents water absorption and expansion in cold conditions, while maintaining its compressive strength and bonding properties. The additive reacts with moisture to form a protective layer that prevents concrete from expanding and cracking due to freezing. This results in improved durability and performance in cold environments.
17. Concrete Composition with Polymethylmethacrylate-(Adamantyl)Acrylate and Bismaleimide Resin
HWAJIN CONSTRUCTION CO LTD, Hwajin Construction, Jang Byeong-ha, 2021
Concrete composition having excellent initial stiffness and excellent basic strength characteristics, as well as improved resistance to salt damage and freeze-thaw resistance. The composition includes 100 parts by weight of polymethylmethacrylate-(adamantyl)acrylate copolymer, 70 to 90 parts by weight of acrylonitrile-butadiene-styrene copolymer, 10 to 30 parts by weight of bismaleimide resin, butanedioldi it provides a super-strength cement concrete composition having improved salt damage and freeze-thaw resistance.
18. Silicone-Coated Recycled Aggregates with Hydrophobic Film and Enhanced Cement-Gel Interface
CHONGDE BUILDING MATERIALS GROUP CO LTD, 2021
Silicone-coated recycled aggregates for enhanced freeze-thaw resistance in concrete, particularly in recycled concrete applications. The coating forms a hydrophobic silicone film on the aggregate surface, reducing water absorption while improving the cement-gel interface. This treatment enables compacted aggregate structures with enhanced compressive strength and improved freeze-thaw durability compared to conventional recycled aggregates.
19. Concrete Composition Incorporating Waste Tire Rubber Particles and Iron Powder
BEIJING URBAN CONSTRUCTION YATAI GOLD CONCRETE CONCRETE CO LTD, 2021
Concrete with enhanced freeze resistance through the incorporation of waste tire rubber particles and iron powder. The composite material combines the natural binding properties of rubber with the mechanical strength of iron particles, forming a durable and environmentally friendly concrete solution. The rubber particles, specifically rubberized tire waste, replace conventional cement and aggregate, while the iron powder enhances the material's mechanical properties. This composite concrete offers improved resistance to freeze-thaw damage, reduced water absorption, and enhanced durability compared to conventional concrete.
20. Concrete Mixture Incorporating Sodium Nitrite for Enhanced Thermal Stability and Early Strength
SHANGHAI PUYING CONCRETE CO LTD, 2021
Antifreeze concrete mixture for protecting concrete structures from freeze-thaw damage. The mixture combines a conventional concrete mixture with sodium nitrite as an early strength agent, which significantly enhances the concrete's resistance to thermal stress. The mixture is prepared by blending the conventional concrete with sodium nitrite solution, followed by a controlled mixing process that incorporates the sodium nitrite solution into the concrete mixture. This results in a concrete with superior thermal stability and early strength properties, enabling it to withstand repeated freeze-thaw cycles without compromising its structural integrity.
21. Concrete Composition with Treated Glass Fibers for Controlled Micro-Bubble Distribution and Enhanced Durability
PENG ZHENFAN, 2021
High-performance antifreeze concrete for structural durability enhancement through controlled micro-bubble distribution and improved workability. The method involves optimizing glass fiber treatment and incorporation into cement matrix, followed by specific concrete formulation and curing parameters. The treated glass fibers enhance micro-bubble formation while maintaining workability, leading to improved freeze-thaw resistance and enhanced durability.
22. Cement Concrete Composition with Ultra-Fast-Hardening Binder and Super-Fast Hardening Agent
Jungang Polytech Co., Ltd., JUNGANG POLY TECH CO.,LTD., Jo Dong-min, 2020
Ultrafast cement concrete composition with enhanced salt resistance and freeze-thaw durability. The composition comprises ultra-fast-hardening binder, fine aggregate, coarse aggregate, ultra-fast hardening agent, and super-fast hardening agent, with improved performance against salt damage and freezing-thawing. The super-fast hardening agent enables rapid curing while maintaining workability and strength. The composition combines the benefits of ultra-fast-hardening cement with improved salt resistance and freeze-thaw durability, making it suitable for road pavements and structural repairs.
23. Basalt Fiber Reactive Powder Concrete with Steel Fibers and Water-Reducing Agent for Enhanced Frost Resistance
JILIN UNIVERSITY, 2020
Basalt fiber reactive powder concrete for seasonal freezing areas with enhanced frost resistance. The concrete combines basalt fiber with a water-reducing agent and incorporates steel fibers to improve durability in the presence of chloride ions and freeze-thaw cycles. The basalt fiber's low elastic modulus and dispersibility enable better distribution of reinforcement within the concrete, while the water-reducing agent helps mitigate chloride-induced damage. This combination provides superior frost resistance compared to steel fiber-based concrete, making it particularly suitable for seasonal freezing areas.
24. Concrete Composite with Alkaline-Modified Rubber Particles for Enhanced Frost Resistance
UNIV WUHAN SCIENCE & TECH, 2019
Antifreeze concrete with improved frost resistance, achieved through the modification of rubber particles in the cement matrix. The modification process involves refluxing hydroxyl groups on the rubber particles under alkaline conditions to enhance their hydrophilicity. This modification enables the rubber particles to better bond with the cement matrix, particularly in freeze-thaw conditions, while maintaining their mechanical properties. The resulting composite material exhibits enhanced frost resistance compared to conventional concrete formulations.
25. Concrete Composition with Integrated Additives and Reinforcements for Enhanced Freeze-Thaw and Thermal Stability
HUZHOU WUMI TECH CO LTD, 2019
High-strength anti-freeze-thaw concrete with enhanced thermal resistance. The concrete combines advanced freeze-thaw protection with improved thermal stability through the incorporation of specific additives and structural reinforcements. This results in enhanced durability and resistance to frost heave in cold climates, while maintaining superior compressive strength compared to conventional concrete formulations.
26. Concrete Composition with Anti-Freeze-Thaw Treatment Incorporating Buffer Material for Enhanced Durability
ZHONGYI NEW MATERIAL RESEARCH INSTITUTE CO LTD, 2019
High-altitude freeze-thaw-resistant road concrete that enhances durability through a novel anti-freeze-thaw treatment. The treatment improves concrete performance by mitigating the detrimental effects of temperature fluctuations on concrete properties, particularly at high elevations where freeze-thaw cycles are prolonged. The treatment achieves this through a buffer material that counteracts the expansion and contraction of concrete caused by temperature changes, thereby preventing cracking and damage.
27. Method for Preparing Concrete with Anti-Freeze-Thaw Additive Enhancing Thermal Expansion and Contraction Properties
ZHONGYI NEW MATERIAL RESEARCH INSTITUTE CO LTD, 2019
Method for preparing high-altitude freeze-thaw-resistant road concrete through the use of a novel anti-freeze-thaw buffer material. The method involves incorporating a specific additive into the concrete mixture to enhance its thermal expansion and contraction properties at low temperatures, thereby mitigating the detrimental effects of freeze-thaw cycles on road surface integrity. The additive improves concrete's resistance to shrinkage and expansion at low temperatures, while maintaining its compressive strength and durability.
28. Concrete Composition with Composite Admixture and Aluminum Oxide Modified Vitrified Microbead Powder
HEBEI JIANYE PREMIXED CONCRETE CO LTD, 2019
A freeze-thaw-resistant concrete that combines enhanced durability with improved thermal insulation properties. The concrete comprises a composite admixture, cement, nano silica, fly ash, coarse aggregate, fine aggregate, and aluminum oxide modified vitrified microbead powder. The admixture combines with water to form a uniform solution, which is then mixed with cement, nano silica, and aggregate. The resulting concrete exhibits superior freeze-thaw resistance while maintaining thermal insulation properties, making it suitable for riverbank applications where temperature fluctuations and water flow can compromise concrete integrity.
29. Method for Integrating Rubber Powder into Concrete to Modify Freeze-Thaw Durability Characteristics
UNIV XIAN ARCHITECTUR & TECH, 2018
A method for optimizing rubber powder aggregate concrete for improved freeze-thaw resistance durability in road and bridge construction. The method involves incorporating rubber powder into conventional concrete formulations to enhance their freeze-thaw durability through a combination of mechanical and chemical properties. The incorporation of rubber powder improves the concrete's resistance to thermal expansion and contraction cycles, while also reducing the formation of micro-cracks and pore structures that contribute to freeze-thaw damage.
30. Concrete Composition with Additives for Enhanced Thermal Resistance and Modified Thermal Conductivity
SHCHEPOCHKINA YULIYA ALEKSEEVNA, Shchepochkina Yuliya Alekseevna, 2018
Enhancing the durability of concrete through improved thermal resistance. The invention involves modifying cement-based concretes to enhance their resistance to freezing temperatures. This is achieved through the incorporation of specific additives and structural modifications that improve the concrete's thermal conductivity and thermal insulation properties.
31. Concrete Composition with Blast Furnace Slag Fine Aggregate and Specified Water Content for Enhanced Freeze-Thaw Resistance
UNIV OKAYAMA, 2017
A concrete composition and method for improving frost damage resistance through the use of blast furnace slag fine aggregate. The composition comprises a fine aggregate containing blast furnace slag fine aggregate, a binder containing cement, water, and a coarse aggregate, with a specific water content of 165 kg/m³. The composition achieves superior freeze-thaw resistance through a unique blend of blast furnace slag fine aggregate and a cement binder, resulting in a concrete with a kinematic modulus of 60% or more. The composition can be produced without adding conventional freeze-thaw resistant additives, achieving a freeze-thaw resistance of 60% or more in 300 freeze-thaw cycles.
32. Concrete Building Blocks with SCM-Enhanced Thermal Insulation and Specialized Aggregate
Shchepochkina Yulia Alekseevna, SHCHEPOCHKINA JULIJA ALEKSEEVNA, SHCHEPOCHINA YULYA ALEKSEEVNA, 2015
Concrete building blocks for low-rise structures that enhance their resistance to frost damage through improved thermal insulation properties. The invention involves the use of a novel concrete mixture formulation that incorporates a combination of supplementary cementitious materials (SCMs) and a specific type of aggregate that provides enhanced thermal insulation. The SCMs enhance the concrete's thermal resistance, while the aggregate provides structural integrity. The formulation enables the production of concrete blocks that can withstand prolonged exposure to frost without compromising their structural performance.
33. Concrete Anti-Freezing Agent with Specific Ratios of Polyacrylamide, Alkyl Benzene Sulfonic Acid Sodium Salt, Ethylene Glycol, and Sodium Carboxymethyl Cellulose
Donghai Construction Group Co., Ltd., DONGHAI CONSTRUCTION GROUP CO LTD, 2015
Concrete anti-freezing agent comprising a combination of polyacrylamide, alkyl benzene sulfonic acid sodium salt, ethylene glycol, and sodium carboxymethyl cellulose. The composition is formulated in specific weight ratios of 1-2 parts polyacrylamide, 0.5-1 part alkyl benzene sulfonic acid sodium salt, 2-4 parts ethylene glycol, and 0.5-1 part sodium carboxymethyl cellulose. The combination provides enhanced freeze protection for concrete compared to conventional anti-freezing agents.
34. Concrete Composition with Polymer-Based Frost Protection and Additives for Enhanced Durability
WUWEI HENGJI COMMERCIAL CONCRETE CO LTD, 2015
High-strength concrete with enhanced frost resistance, designed for critical infrastructure applications like dams, bridges, and buildings. The formulation combines advanced polymer-based frost protection agents with specific additives to achieve superior performance in extreme winter conditions. The formulation provides enhanced durability, improved resistance to thermal expansion, and enhanced service life compared to conventional concrete formulations.
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