VOC Free Paint Formulations
Traditional paint formulations rely heavily on volatile organic compounds (VOCs) as solvents and binding agents, typically containing 250-400 grams per liter of VOCs. These compounds, essential for paint flow, leveling, and curing characteristics, pose significant environmental and health challenges during application and curing processes.
The fundamental challenge lies in maintaining paint performance characteristics—viscosity, coverage, durability, and cure times—while eliminating volatile organic compounds that have historically been crucial to these properties.
This page brings together solutions from recent research—including epoxy resin-based compositions with specific epoxy values, biobased non-isocyanate poly(hydroxyl urethane) coatings derived from plant oils, and high-solid coating systems with reactive acrylic polyol resins. These and other approaches demonstrate how manufacturers can achieve VOC-free formulations while maintaining or enhancing coating performance for industrial applications.
1. Epoxy Resin-Based Coating Composition with Specific Epoxy Value and Fast-Drying Corrosion-Resistant Properties
BASF COATINGS GMBH, 2024
A low-VOC epoxy resin-based coating composition for engineering applications that combines fast drying properties with enhanced corrosion resistance. The composition comprises an epoxy resin with a specific epoxy value range, combined with a curing agent and optional drying agent. The epoxy resin component provides excellent mechanical properties, while the curing agent enhances the coating's performance in harsh environments. The composition achieves fast drying times while maintaining superior salt resistance, making it suitable for applications requiring rapid curing and high-performance coatings in industrial environments.
2. Biobased Non-Isocyanate Poly(Hydroxyl Urethane) Coatings Synthesized from Epoxidized Plant Oils and Biobased Polyamines
VON HOLZHAUSEN, 2024
Biobased non-isocyanate poly(hydroxyl urethane) (NIPU) coatings for flexible substrates achieve supple and durable properties through a novel synthesis pathway involving epoxidized plant-based oils and biobased polyamines. The process involves chemical insertion of carbon dioxide into epoxidized oils to produce cyclic carbonate monomers, which are then crosslinked with biobased polyamines to form the NIPU polymer network. The resulting coatings exhibit exceptional mechanical properties, including high elongation to break strain, and can be formulated into flexible substrates for applications like leather alternatives and automotive coatings.
3. Flexible Packaging System with VOC Reduction via Heat-Based Drying and Exhaust Gas Combustion
Sujeong Industrial Co., Ltd., SOOJUNG CORP, 2024
Flexible packaging manufacturing system that significantly reduces volatile organic compound (VOC) emissions from gravure printing and drying processes without sacrificing speed. The system uses eco-friendly ink compositions and dries them using heat instead of solvent evaporation. Exhaust gases from drying and lamination are burned to remove VOCs before release.
4. Paint Composition with Main Resin, Curing Agent, and Antifoaming Agent for Reduced VOC Emissions
HD HYUNDAI HEAVY INDUSTRIES CO LTD, 2024
Manufacturing a paint that can reduce volatile organic compound (VOC) emissions and secure excellent painting workability. The composition includes a main portion containing a main resin, a curing agent portion containing a curing agent, and an antifoaming agent.
5. Low-VOC Coating Composition with Epoxy Compound, Reactive Diluent, Curing Agent, and Dioxolane Derivative
CHUGOKU MARINE PAINTS LTD, 2023
A low-VOC coating composition for coatings, substrates, and films that eliminates the need for benzyl alcohol while maintaining excellent performance. The composition comprises an epoxy compound with an epoxy equivalent of more than 200, a reactive diluent, a curing agent, and a dioxolane derivative. The epoxy compound provides the necessary mechanical properties, while the reactive diluent and curing agent enable the composition to achieve the desired viscosity without benzyl alcohol. The dioxolane derivative enhances film formability and curing properties, making the composition suitable for a wide range of coating applications.
6. High-Solid Coating Composition with Acid Group-Containing Acrylic Monomer and Reactive Acrylic Polyol Resin
KCC Corporation, KCC CORP, 2022
High-solid coating composition with reduced VOC content, ensuring excellent pot life and workability while maintaining drying properties. The composition comprises an ethylenically unsaturated monomer, an acid group-containing acrylic monomer, and a reactive acrylic polyol resin prepared by polymerizing a mixture of diluents, with a curing agent. The polyol resin enhances film properties while controlling VOC emissions, achieving a solid content of 70% or more.
7. Protective Coating Composition for Steel Structures with High-Solid Alkyd Resin and Additive Blend
JIANGSU CHAMPION TECHNOLOGY GROUP CO LTD, 2021
High solid, low VOC protective coating for steel structures that has improved performance, durability, and reduced environmental impact compared to traditional coatings. The coating contains specific components like high-solid alkyd resin, calcium carbonate, organic bentonite, humectant, dispersant, desiccant, and anti-skinning agent in optimized ratios. The coating provides high solid content, low toxicity, good adhesion, flexibility, corrosion resistance, weather resistance, hardness, and smoothness. The coating preparation involves mixing the components in steps to disperse them uniformly.
8. Acrylic Resin Coating with Specific DEA and 2-(3-Chlorophenyl)prop-2-enoic Acid Molar Ratios for Waterborne Applications
BENTENG PAINT IND SHANGHAI CO LTD, 2021
Low-VOC acrylic resin coating and its preparation method for waterborne coatings that addresses the limitations of conventional waterborne coatings. The coating comprises an acrylic resin with specific molar ratios of diethanolamine (DEA) and 2-(3-chlorophenyl)prop-2-enoic acid, combined with surfactants, a curing agent, a defoamer, and pigments. The formulation achieves improved water resistance, mechanical properties, and stain resistance while maintaining excellent film formation and adhesion.
9. Coating Composition with Acrylic Polyol Resin and Radical Polymerization Initiator
KCC Corporation, KCC CORP, 2021
A coating composition for metal surfaces that reduces VOC emissions while maintaining excellent pot life and drying properties. The composition comprises an acrylic polyol resin with an acid value between 10 and 30 mgKOH/g, a curing agent, and a radical polymerization initiator. The curing agent enhances the curing process, while the polyol resin improves the coating film's mechanical properties. The composition achieves reduced VOC emissions through the curing agent's reaction with the polyol resin, resulting in a more environmentally friendly coating solution.
10. Polyurethane Coating with Specific Resin-to-Solvent Weight Ratio and Novel Solvent Blend
FOSHAN SHUNDE GUDELI PAINT CO LTD, 2020
A low-VOC polyurethane (PU) coating with improved performance characteristics. The coating is prepared through a novel mixing process that combines a high-performance resin with a specific blend of solvents. The resin is formulated with a specific weight ratio of 5118 to solvent, and the solvent blend is optimized for improved flow and dispersion properties. The resulting PU coating exhibits enhanced abrasion resistance, acid and alkali resistance, and hardness, all while maintaining low volatile organic compound (VOC) content.
11. Aqueous Dispersion with Acrylic Binder and Methylene Bridged Copolymer Adsorbent Particles
ROHM AND HAAS CO, 2020
Aqueous dispersion and coating composition containing the same, comprising an acrylic binder dispersion and a specific polymeric adsorbent particle mixture. The dispersion contains acrylic binder particles, while the adsorbent particles contain a methylene bridged copolymer of divinylbenzene and a monovinyl aromatic monomer. The adsorbent particles are added to the acrylic binder dispersion before it is formulated into the coating, eliminating the need for additional VOC removal steps. The dispersion and coating composition achieve VOC levels below 800 ppm, making it suitable for applications requiring low-VOC coatings.
12. VOC-Free Polyurethane Coatings with Aromatic Pre-Polymer and Isocyanate Terminals
CONSTRUCTION RESEARCH & TECHNOLOGY GMBH, 2019
Polyurethane coatings for structures like parking decks and garages that achieve VOC-free formulations while maintaining high performance properties. The coatings contain an aromatic polyurethane pre-polymer with isocyanate terminal groups, a solvent blend, a catalyst, and fillers. The VOC content is less than 97 g/L, with the pre-polymer achieving a molecular weight of 500-10000 g/mol and an NCO/OH ratio of 1.1-5. The coatings exhibit excellent adhesion, durability, and resistance to deicing salts, while the VOC-free formulation enables compliance with stringent VOC regulations.
13. Solvent-Free Epoxy Coating Composition with Aliphatic and Aromatic Amine Resin Curing Agent
KCC Corporation, KCC CORPORATION, 2019
Solvent-free epoxy coating composition for floors that achieves excellent low-temperature curing properties. The composition comprises a main portion of solventless epoxy resin, sieving pigment, reactive diluent, non-reactive diluent, color pigment, and additives. The main portion contains 20-40% epoxy resin and a curing agent containing aliphatic and aromatic amine resins with a curing accelerator. The curing agent and curing accelerator combine to form a curing agent portion with 20-40% epoxy resin content and a curing agent portion with 30-50% non-reactive diluent content.
14. Binder Composition with Ethyl Acrylate-Based Dispersion Polymer Exhibiting Low VOC Emission and Defined Particle Size Distribution
BASF SE, 2019
A binder composition comprising a dispersion polymer with a glass transition temperature of ≤20°C, comprising ethyl acrylate in copolymerized form, which exhibits extremely low volatile organic compound (VOC) emission when used to produce a solidified or set material. The dispersion polymer is prepared through aqueous polymer dispersion or polymer powder production, with the dispersion polymer having a particle size distribution of ≥10 nm. The dispersion polymer is combined with mineral binders like cement to produce a solidified or set material that meets the low VOC emission requirements of the European Green Building Code (GEV) EMICODE.
15. Water-Based Single-Component Paint with Epoxy-Modified Acrylic Emulsion and Dual Hammering Agents
HEBEI CHENYANG IND & TRADE GROUP CO LTD, 2019
Water-based single-component ultra-low VOC quick-drying orange paint for surfaces, comprising a waterborne epoxy-modified acrylic emulsion, hammering agent Raybo, hammering agent CN-680, environmentally friendly packing, and a pH adjuster. The paint achieves excellent performance characteristics, including fast drying, low VOC emissions, and excellent surface finish quality, while maintaining durability and resistance to environmental pollutants.
16. Acrylic Paint Composition with Water-Soluble Polymer Additive for Enhanced Film Properties
DANYANG BOYUAN SAFETY PRODUCTION SERVICE CO LTD, 2019
Acrylic paint with improved performance characteristics for environmentally friendly coatings. The paint combines the benefits of water-based and solvent-based paints by introducing a novel, water-soluble polymer additive that enhances film properties while maintaining environmental compatibility. The additive improves paint flow, adhesion, and thermal stability, enabling faster drying times and better heat resistance compared to conventional water-based paints.
17. Eco-Coating Composition with Inorganic Mineral Powder and Nitrogen-Polymerized Latex Polymer
DAMEITAIKANG ECOLOGICAL TECHNOLOGY CO LTD, 2018
A multifunctional eco-coating composition that is free of formaldehyde and VOCs. The coating composition contains 50-90% inorganic mineral powder, 5-60% latex polymer, thickener, surfactant, and pigment. The latex polymer is made by polymerizing monomers in a nitrogen-protected reactor. The surfactant improves compatibility between the inorganic minerals and latex polymer to prevent settling, segregation, and aggregation. The coating provides low VOCs compared to solvent-based coatings due to the use of a lower viscosity latex polymer and reduced organic solvents.
18. Interior Latex Paint with Low-VOC Composition Incorporating Polymers, Cellulose Ether, and Additives for Enhanced Stability and Light Blocking
CHENGDU BARDESE PAINT CO LTD, 2018
A low-VOC, environmentally friendly interior latex paint that achieves clean taste while meeting stringent health and environmental standards. The paint combines a defoaming agent with a special balance of polymers, cellulose ether, and other additives to create a superior performance paint system. The formulation incorporates rutile titanium dioxide, calcined clay, and talc for superior light blocking, while the pH regulator maintains optimal paint stability. This innovative combination enables a paint with exceptional clean taste while minimizing environmental impact.
19. Colorant Composition with Copolymer Surfactant for Reduced Volatile and Hazardous Constituents in Latex Paints
COLUMBIA INSURANCE CO, 2018
Colorant composition for aqueous latex paints that achieves environmental sustainability through reduced volatile non-aqueous constituents (VNCs), alkylphenol ethoxylates (APEs), crystalline silica, and formaldehyde. The composition is formulated with a copolymer surfactant comprising specific monomers that enable the removal of these environmentally undesirable substances while maintaining film properties. The surfactant enables the incorporation of VNCs, APEs, crystalline silica, and formaldehyde into the paint formulation without compromising performance characteristics.
20. VOC-Free Primer Coating with Hybrid Curing System and Oxirane Ring-Containing Resin for Enhanced Interlayer Adhesion
CHOI JUNG SEOK, TNS CO LTD, TNS Co., Ltd., 2017
A VOC-free primer coating for concrete surfaces that achieves superior interlayer adhesion through a novel hybrid curing system. The primer composition combines an environmentally friendly curing agent with a water-soluble or water-dispersible resin, achieving a curing network structure that enables strong adhesion between the primer layer and subsequent topcoat layer. The curing agent contains an oxirane ring-containing resin that forms a polymer fusion structure with the resin layer, while the curing agent itself has a viscosity of 200 cps or less. This hybrid system enables effective curing through chemical and physical hybrid curing mechanisms, resulting in a water-soluble or water-dispersible primer coating that replaces traditional oil-based coatings while maintaining excellent performance characteristics.
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