Heat exchanger fouling in HVAC systems leads to significant performance degradation, with studies showing up to 30% reduction in heat transfer efficiency within the first year of operation. Surface deposits accumulate at rates between 0.1-0.5 mm per month under typical operating conditions, creating thermal barriers that increase energy consumption and maintenance costs.

The engineering challenge lies in developing coatings that simultaneously prevent biological growth, mineral scaling, and particulate adhesion while maintaining optimal heat transfer properties across varying temperature and humidity conditions.

This page brings together solutions from recent research—including fluorine-free super-hydrophobic coatings with modified silicon dioxide, dual-function transition metal oxide surfaces, and nanoparticle-infused antifouling treatments. These and other approaches focus on practical implementation strategies that balance durability, environmental impact, and thermal performance in real-world HVAC applications.

1. Fluorine-Free Super-Hydrophobic Coating with Modified Silicon Dioxide and Silicone Resin for Heat Exchangers

Hangzhou Ximei New Material Technology Co., Ltd., 2025

A fluorine-free wear-resistant super-hydrophobic coating for heat exchangers that combines excellent anti-corrosion and weather resistance properties with enhanced mechanical durability. The coating achieves super-hydrophobic performance without fluorine elements, addressing environmental concerns while maintaining superior performance characteristics. The coating's thickness can be tailored to achieve specific performance requirements, including wear resistance, corrosion protection, and condensation heat transfer efficiency. The preparation method involves modifying silicon dioxide and silicone resin surfaces to create the super-hydrophobic coating, which can be applied to heat exchangers for improved performance in various industrial applications.

2. Hydrophobic Coating Comprising Fluorosilicone Acrylic Resin and Modified Alumina Particles for Evaporator Surfaces

TONGJI UNIVERSITY, 2024

A hydrophobic coating for cold storage evaporator surfaces that prevents frost formation through a novel combination of fluorosilicone acrylic resin and hydrophobic alumina particles. The coating is prepared through a simple room-temperature cold spraying process, enabling rapid and cost-effective application. The hydrophobic alumina particles are modified with an organic fluorine-containing chain segment to prevent clumping and uneven dispersion, while the fluorosilicone acrylic resin provides mechanical strength and thermal stability. This coating achieves superior anti-frost performance compared to conventional methods, with enhanced durability and system reliability.

3. Heat Exchanger with Dual-Function Hydrophilic Coating Comprising Transition Metal Oxides for Selective Antibacterial and Deodorizing Actions

LG ELECTRONICS INC, 2024

A heat exchanger with integrated antibacterial and deodorizing surfaces that selectively perform these functions based on operating conditions. The heat exchanger features a hydrophilic coating comprising a first transition metal oxide that reacts with moisture to form an acidic environment, while a second transition metal oxide or post-transition metal oxide catalytically degrades when exposed to air. This dual-function coating enables continuous performance of both antibacterial and deodorizing properties through dynamic surface chemistry, with the coating composition optimized for optimal performance across refrigeration and drying modes.

CN118066918A-patent-drawing

4. Method for Self-Cleaning Air Conditioner Heat Exchanger Fins Using Hydrophilic and Oleophobic Coating

GD MIDEA AIR-CONDITIONING EQUIPMENT CO LTD, Guangdong Midea Refrigeration Equipment Co., Ltd., 2023

A self-cleaning method for air conditioning systems that prevents oil contamination on heat exchanger fins. The method involves applying a hydrophilic and oleophobic coating to the heat exchanger fins, which enables the formation of large contact areas between oil droplets and the coating surface. During the cooling cycle, the oil droplets crystallize, and during the condensation cycle, the crystals are removed from the fins through the condensed water flow. This process creates a continuous cleaning mechanism that prevents oil from accumulating on the heat exchanger fins.

5. Hydrophobic Coating for Radiators with Silicone Emulsion and Formaldehyde-Teramine Resin Cross-Linking

Jiangmen Paint Factory Co., Ltd., JIANGMEN PAINT FACTORY CO LTD, HISENSE AIR CONDITIONING CO LTD, 2022

A hydrophobic coating for air-conditioning radiators that prevents water droplets from forming ice on the radiator surface during heating. The coating is prepared using a modified silicone emulsion as the base film-forming material, combined with formaldehyde-teramine formaldehyde resin for cross-linking. The coating formulation balances water-repellent properties with improved thermal resistance, enabling efficient heat dissipation while maintaining air conditioner performance.

6. Nano-Metal and Oxide-Infused Acrylic Coating for Heat Exchanger Surfaces with Synergistic Antimicrobial Properties

Guangzhou Huigu Chemical Co., Ltd., GUANGZHOU HUMAN CHEMICALS CO LTD, 2022

Antimicrobial hydrophilic coating for air-conditioning heat exchanger surfaces that combines durable antibacterial and antifungal properties with water resistance. The coating comprises nano-metals, oxides, and acrylic resin, with a total mass of 100 parts. The coating's antibacterial and antifungal performance is enhanced by strategically incorporating specific antibacterial agents, such as silver and zinc, in the coating formulation. The coating achieves superior performance through a synergistic effect between the metal components and the acrylic resin, maintaining its hydrophilic properties even after repeated scouring.

CN112724770B-patent-drawing

7. Heat Exchanger with Polymer Coated Fins Featuring Brush-Like Chain Aggregate for Condensation Prevention

INST NATIONAL COLLEGES TECH JAPAN, 2022

A heat exchanger for refrigeration systems that prevents water droplet condensation on heat transfer fins through a novel polymer coating. The coating comprises a brush-like polymer chain aggregate with controlled mobility against water droplets, which forms a stable liquid layer that suppresses water droplet adhesion and ice formation. This coating maintains its liquid state even in humid environments, ensuring optimal heat transfer efficiency. The coating can be applied to heat transfer surfaces and can be maintained through continuous replenishment of the liquid layer.

8. Silicon Oxide Coating Process for Heat Exchanger Surfaces with Non-Continuous Film and Variable Surface Roughness

SIOX APS, 2022

A method for reducing fouling on heat exchanger surfaces through a novel silicon oxide coating process. The coating, comprising a non-continuous film of silicon oxide, achieves superior anti-fouling properties compared to conventional coatings by minimizing surface roughness while maintaining thermal stability. The process enables the creation of coated heat exchangers with reduced fouling characteristics, particularly for complex geometries, without the need for continuous coatings or conformal coverage. The coating's unique composition and curing process enable effective adhesion to metal surfaces while maintaining mechanical integrity.

WO2022002392A1-patent-drawing

9. Heat Exchanger with Nanoparticle-Infused Antifouling Coating for Dust Suppression

PANASONIC IP MANAGEMENT CORP, 2021

An air conditioner with a heat exchanger featuring an antifouling coating that suppresses dust adhesion through a novel combination of nanoparticles and a specially developed coating film. The coating film, which is integrated into the heat exchanger fins, enables effective dust suppression while minimizing cross-linking forces from dew condensation. This integrated approach addresses conventional issues of dust accumulation and bacterial growth in air conditioning systems.

JP2021116951A-patent-drawing

10. Condenser Heat Exchange Pipe with Alternating Hydrophilic and Water-Repellent Coating Layers

LG ELECTRONICS INC, 2021

Condenser design for air conditioning systems that enhances heat transfer efficiency through a novel coating strategy. The condenser comprises a heat exchange pipe with alternating hydrophilic and water-repellent coating layers along its length. The hydrophilic layer forms a uniform film on the inner surface, while the water-repellent layer creates a barrier against condensed water droplets. This dual-layer approach prevents the formation of water droplets that can impede heat transfer, while maintaining the condensation process. The coating pattern can be designed to optimize performance across the condenser's operating range.

KR20210054901A-patent-drawing

11. Heat Exchanger with Hydrophobic Polymer Coating for Scaling Prevention

Tsinghua University Tianjin High-end Equipment Research Institute, TIANJIN RESEARCH INSTITUTE FOR ADVANCED EQUIPMENT TSINGHUA UNIVERSITY, 2021

Anti-fouling air source heat pump heat exchanger that prevents scaling through a unique surface treatment. The coating comprises a hydrophobic polymer layer that reduces surface energy on the spiral coil's inner surface, preventing mineral particles from adhering. A low surface energy layer enhances wear resistance. This innovative approach addresses the conventional scaling issues in air conditioning heat exchangers by targeting the underlying physical mechanisms of fouling rather than relying solely on chemical descaling methods.

CN212842324U-patent-drawing

12. Heat Exchanger Tube with Super-Oleophobic Coating and Integrated Finned Design

TECHNICAL INSTITUTE OF PHYSICS AND CHEMISTRY CHINESE ACADEMY OF SCIENCES, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, 2021

A heat exchanger with a super-oleophobic coating on the outside of the tube that prevents grease droplets from adhering to the tube surface. The coating features a surface with a contact angle greater than 150°, creating a hydrophobic barrier that prevents oil droplets from penetrating the tube. The coating is applied to the tube's exterior surface, extending along its length, and can be integrated with the tube's finned design. This prevents fouling and ensures efficient heat transfer while maintaining the tube's structural integrity.

13. Hydrophobic Anti-Icing Coating with Enhanced Oil Repellency for Heat Pump Evaporators

SU BIN, Su Bin, 2021

A coating for air source heat pumps that prevents frost formation on the evaporator surface while maintaining efficient defrosting performance. The coating comprises a hydrophobic anti-icing material with enhanced oil repellency properties, designed to prevent frost accumulation on the heat exchanger surface. This coating provides superior defrosting capabilities compared to conventional coatings while maintaining the heat pump's efficiency and environmental benefits.

14. Composite Heat Exchanger Fin Material with Dual-Layer Nano-Scale Hydrophobic Coating

Midea Group Co., Ltd., MIDEA GROUP CO LTD, Guangdong Midea Refrigeration Equipment Co., Ltd., 2021

Composite material for heat exchanger fins that prevents condensation and frost through a dual-layer nano-scale coating. The coating comprises a hydrophobic primer layer and a superhydrophobic nanostructured top layer, where the nanostructured layer is created from hydrophobic nanoparticles with a particle size range of 5-300 nm. This nanostructured layer prevents water droplets from entering the gap and converting to the Cassie state, while maintaining hydrophobicity. The primer layer enhances wear resistance and adhesion without compromising frost prevention. The composite material demonstrates superior frost resistance compared to conventional superhydrophobic coatings.

15. Superhydrophobic Coating Agent for Heat Exchanger Surface with Controlled Droplet Formation Mechanism

SHANGHAI FOURIET REFRIGERATION EQUIPMENT CO LTD, 2020

A superhydrophobic coating agent, heat exchanger, and heat exchanger surface treatment method that enables continuous defrosting of heat exchangers through controlled liquid droplet formation. The coating agent forms stable, uniform droplets of liquid onto the heat exchanger surface, which then break apart and freeze into a solid, non-wetting layer. This continuous droplet formation mechanism enables the heat exchanger to maintain a stable liquid film, eliminating the need for intermittent heating and defrosting operations. The treatment method can be applied to various heat exchanger surfaces and can be integrated into existing heat exchanger designs for enhanced performance and environmental sustainability.

16. Heat Exchanger Coating with Hydrophilic Nanoparticles and Fluorine Compound Incorporation

PANASONIC IP MANAGEMENT CO LTD, 2020

A heat exchanger with an antifouling coating featuring hydrophilic inorganic nanoparticles and a fluorine compound. The coating has a controlled particle size of less than 100 nm and maintains a surface roughness of 2.5 nm to 100 nm. The fluorine compound is incorporated within the coating film at concentrations of 0.1% to 10% by weight, ensuring both hydrophilicity and oil repellency. This dual-function coating provides effective antifouling properties against both dry stains and water-based contaminants, enabling self-cleaning performance without compromising the heat exchanger's performance.

17. Hydrophobic Coating for Heat Exchanger Fins in Outdoor Air Conditioning Units

MIDEA GROUP CO LTD, Midea Group Co., Ltd., 广东美的制冷设备有限公司, 2020

A coating for outdoor air conditioning units that prevents ice formation on the wind guide ring by modifying the surface properties of the heat exchanger fins. The coating creates a hydrophobic surface that prevents water droplets from forming on the fins, thereby preventing ice accumulation and frost formation. This coating enables the outdoor unit to maintain efficient operation while preventing ice buildup, which can cause motor damage and system malfunction.

CN210030527U-patent-drawing

18. Wet Membrane for Heat Exchangers with Lithium Salt-Treated Hydrophilic Surface and PTFE Matrix Incorporating Porogen

JI JINXUE, 2020

A modified wet membrane for air-conditioning external heat exchangers that enables self-cleaning and enhanced dehumidification performance. The membrane comprises a dense skin layer with a hydrophilic surface treated with a lithium salt and a porogen, which significantly increases water vapor permeability and enhances the membrane's self-cleaning capabilities through improved surface interaction with water vapor. The membrane's porogen is incorporated into the polytetrafluoroethylene (PTFE) matrix, providing controlled pore size and density, while maintaining the membrane's mechanical integrity. This innovative design enables the membrane to effectively remove airborne particulate matter and pollutants from the air stream, while maintaining its self-cleaning properties.

CN110743378A-patent-drawing

19. Graphene-Based Superhydrophobic Coating with Water Contact Angle Greater than 150° for Enhanced Durability on Heat Exchanger Surfaces

MIANYANG MAXWELL TECH CO LTD, 2019

A water-based graphene superhydrophobic self-cleaning coating for air-conditioning heat exchangers that achieves superior performance in condensation control and corrosion protection while eliminating the need for harsh solvents. The coating, comprising a graphene-based surface layer, exhibits a water contact angle greater than 150°, enabling effective water management and protection against ice formation. The coating's wear resistance properties are demonstrated through friction tests on prepared aluminum foil surfaces, demonstrating superior durability compared to conventional coatings.

20. Heat Exchanger with Nanoparticle-Based Antifouling Coating Having Controlled Surface Morphology

PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD, 2018

Heat exchanger for preventing dry dirt adhesion in applications requiring high-temperature heat transfer, such as air conditioning units. The heat exchanger features a nanoparticle-based antifouling coating with a unique surface morphology that controls dry dirt adhesion. The coating's surface features an arithmetic average grain size between 2.5 and 100 nanometers, creating an uneven surface that prevents dry dirt from adhering. The coating is applied to the heat exchanger surface, where it forms a durable, hydrophobic barrier that prevents dry dirt particles from accumulating. This surface morphology is achieved through a proprietary nanoparticle composition that maintains its surface irregularities within specified limits.

WO2018225275A1-patent-drawing

21. Heat Exchanger with Integrated Anti-Frost Mechanism and Optical Frost Detection

22. Heat Exchanger with High-Density Fins and Hydrophobic Coating for Frost Prevention

23. Water-Based Coating for Heat Exchanger Fins with Hydrophilic and Hydrophobic Particle Integration

24. Multi-Layer Coating System for Heat Exchanger Surfaces with Sequential Teflon and Primer Layers

25. Single-Step Coating Agent for Aluminum Heat Exchanger Surfaces with Integrated Corrosion Resistance and Hydrophilicity

Get Full Report

Access our comprehensive collection of 28 documents related to this technology