Cold Cranking Capacity Enhancement in Engine Lubricants
Modern engine lubricants face significant cold-start challenges, with oil viscosity increasing exponentially as temperatures drop below -20°C. At -30°C, oil flow can decrease by over 95% compared to operating temperature, creating critical moments where metal-on-metal contact occurs before proper lubrication is established. This phenomenon contributes to approximately 60% of total engine wear during its operational lifetime.
The fundamental challenge lies in developing formulations that provide sufficient cold-flow properties while maintaining viscosity stability and wear protection across the engine's operating temperature range.
This page brings together solutions from recent research—including dual poly(meth)acrylate viscosity modifiers with temperature-dependent association, propylene-based copolymers with optimized glass transition temperatures, and novel pour-point depressants with controlled molecular weight distribution. These and other approaches provide practical pathways to enhance cold cranking performance without compromising high-temperature protection or oxidation stability.
1. Viscosity Index Improver Composition with Dual Poly(meth)acrylate Structure Exhibiting Temperature-Dependent Association
IDEMITSU KOSAN CO LTD, 2025
Viscosity index improver composition for lubricating oils, comprising a combination of two poly(meth)acrylates, one having a diol group and the other having a boronic acid ester group, which exhibit a unique temperature-dependent association behavior that maintains viscosity stability across a wide temperature range. The composition is particularly effective in lubricating oils used in automotive and industrial applications, where maintaining viscosity stability is critical for optimal performance and wear protection.
2. Lubricating Oil Composition with Propylene-Based Copolymer and Base Oil
MITSUI CHEMICALS INC, 2024
Lubricating oil composition with improved low-temperature viscosity characteristics, comprising a specific copolymer (A) and a base oil (B), wherein the copolymer (A) is a propylene-based copolymer with an intrinsic viscosity of 0.45-2.3 dl/g and a glass transition temperature of -20 to 15°C, and the copolymer (A) is present in a concentration of 0.1-50 parts by mass per 100 parts by mass of the total composition.
3. Lubricating Oil Composition with Defined Boron-to-Calcium Ratio in Calcium-Based Detergent and Magnesium-Based Detergent Concentration
ENEOS CORP, 2024
A lubricating oil composition for internal combustion engines that achieves both excellent Low Speed Pre-Ignition (LSPI) suppression and fuel saving performance. The composition comprises a lubricating base oil and a metal-based detergent containing a calcium-based detergent with a specific boron-to-calcium ratio and a magnesium-based detergent within defined concentration ranges. The boron-to-calcium ratio in the calcium-based detergent is critical to achieving both LSPI suppression and fuel saving performance.
4. Lubricating Oil Composition with Magnesium and Calcium Salicylates and Molybdenum-Based Friction Modifier
ENEOS CORP, 2024
Lubricating oil composition for internal combustion engines with improved fuel efficiency, comprising a lubricating base oil, magnesium salicylate, calcium salicylate, and a molybdenum-based friction modifier, optionally including anti-wear agents, antioxidants, and dispersants.
5. Lubricating Oil Composition with Mineral Oil Base and Magnesium Salicylate Detergent
ENEOS CORP, 2024
Lubricating oil composition for internal combustion engines that combines high fuel efficiency with low-speed pre-ignition (LSPI) reduction. The composition comprises a mineral oil-based base oil with a specific viscosity range and magnesium salicylate as a metallic detergent, in a specific concentration range. The combination enables both improved fuel economy and reduced LSPI events in downsized turbocharged engines.
6. Lubricating Oil Composition with Calcium-Containing Detergent and Silicon-Containing Additive
INFINEUM INTERNATIONAL LTD, 2024
Lubricating oil composition for reducing Low Speed Pre-Ignition (LSPI) events in direct injection-spark ignition engines, comprising a base oil, a calcium-containing detergent providing a calcium content of at least 0.08 wt.%, and a silicon-containing additive providing a silicon content of at least 12 ppm by weight. The composition can be used to lubricate the crankcase of the engine, reducing the occurrence of LSPI events.
7. Engine Lubricating Oil Composition with Mineral Base, Low Molecular Weight Polymer, and Molybdenum-Based Friction Modifiers
IDEMITSU KOSAN CO LTD, 2024
A lubricating oil composition for engines with low surface roughness, particularly suitable for hybrid and idling stop mechanisms, comprising a mineral base oil, a polymer with a weight average molecular weight of 100-15,000, and a molybdenum-based friction modifier. The composition has a kinematic viscosity of 35.0 mm2/s or less at 40°C, and the polymer content is 0.1-5.0% by mass. The molybdenum-based friction modifier contains two or more selected from binuclear molybdenum dithiocarbamate, trinuclear molybdenum dithiocarbamate, and molybdenum amine complex, and the molybdenum content is 50-2,000 ppm by mass.
8. Lubricating Oil Compositions with Functionalized Olefin Copolymers and Sulfurized Fatty Acid Esters
INFINEUM INTERNATIONAL LTD, 2024
Lubricating oil compositions for internal combustion engines that exhibit improved oxidation, wear, and anti-corrosion characteristics. The compositions comprise a combination of additives, including functionalized olefin copolymers, sulfurized fatty acid esters, and other components, that work together to provide enhanced performance in gasoline and diesel engines. The compositions have specific properties, such as low sulfated ash content, high soot dispersancy, and controlled base number, that enable them to meet the demands of modern engines while minimizing environmental impact.
9. Lubricant Composition with Functionalized Hydrogenated Polymer of Conjugated Dienes and Controlled Molecular Weight and Functionality Distribution
INFINEUM INT LTD, 2024
Lubricant compositions for internal combustion engines, comprising a base oil and a dispersant viscosity index improver (DVI) additive, wherein the DVI is a functionalized, hydrogenated polymer of conjugated dienes, such as isoprene or butadiene, having a controlled molecular weight distribution and a functionality distribution of 3.5 or less. The polymer is selectively hydrogenated to produce a polymer with a molecular weight distribution of less than 2, and then functionalized with amide, imide, or ester groups. The lubricant compositions exhibit improved soot dispersancy, wear protection, and cleanliness in engine applications, particularly in compression-ignited engines.
10. Lubricating Oil Compositions with Metal Alkanoates Featuring Quaternary Carbon Structure
INFINEUM INT LTD, 2024
Lubricating oil compositions for heavy-duty diesel engines that exhibit improved friction characteristics and wear protection, comprising a base oil, detergent, and one or more metal alkanoates having a quaternary carbon atom at the 2 position and/or at the 2' position. The metal alkanoates are represented by the Formula (I): R1R2R3COOM, where R1, R2, and R3 are alkyl groups, and M is a metal ion. The compositions have improved wear protection, reduced friction, and low foaming properties, while maintaining a low total base number impact.
11. Copolymer Additive Comprising Formula (A) Units and Dialkyl Fumarate Monomers
INNOSPEC LTD, 2023
A copolymer additive for improving low-temperature properties of middle distillate fuels, comprising units of formula (A) and dialkyl fumarate monomers of formula (D), that counteracts negative interactions between nitrogen-containing detergents and wax anti-settling additives, thereby preventing precipitation and sedimentation of waxes in fuels at low temperatures.
12. Effect of Low Heat Rejection on Performance and Emission Characteristics of a 4-Stroke Diesel Engine
B. Omprakash, R. Ganapathi - REST Publisher, 2023
Due to rapid depletion of natural resources, the cost of petroleum fuels continues to rise, making them unaffordable for the average person.This is especially true in the Indian context.Consequently, C.I. requires a variety of fuel alternatives.The value of engines is rising.The improvement of C.I.'s thermal efficiency is the subject of extensive research.Powerhouse of the High-Tech Industry.Only roughly one-third of the thermal energy from the fuel is transferred to meaningful work by even the most efficient engine; the other two-thirds are wasted as exhaust and coolant.If energy loss can be minimized, Engine performance will increase.Researchers and specialists agree on a number of approaches for improving Engine performance.The idea of a Low Heat Rejection (LHR) Engine is one of the most promising.By utilizing thermally insulated parts, the performance of the LHR Engine can be enhanced.These parts not only improve thermal efficiency but also reduce heat loss to the environment.Various insulations, including ceramic coating on the inner surface of the cylinder head and a 2mm air ga... Read More
13. Engine Oil Lubricant Compositions with Low Viscosity and Volatility Base Oil Exhibiting Reduced Evaporation Rate
EXXONMOBIL RES & ENG CO, 2023
Low viscosity engine oil lubricant compositions that provide improved fuel efficiency and engine wear protection while maintaining low oil consumption over a broad temperature range. The compositions comprise a low viscosity and low volatility base oil that exhibits unexpectedly low evaporation rate compared to conventional base oil combinations with similar Noack levels. The engine oil lubricant compositions are particularly suitable for use in direct injection engines, gasoline engines, and diesel engines, and are particularly effective as OW-4, 0W-8, OW-12, and OW-16 viscosity grade engine oils.
14. Comb Copolymer Viscosity Modifiers Comprising Hydrogenated Polybutadiene-Based (Alk)Acrylate Ester Components
INFINEUM INTERNATIONAL LTD, 2023
Comb copolymer viscosity modifiers for lubricating oils, comprising a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer, a C3-C8 alkyl (alk)acrylate ester monomer, a C12-C24 alkyl (alk)acrylate ester monomer, and a C1-C18 alkyl-endcapped or C6-C20 aryl-, aralkyl-, or alkaryl-endcapped C2-C6 oxyalkyl or C2-C6 oligo(alkylene glycol)-based (alk)acrylate ester monomer. The copolymers exhibit improved low-temperature properties, high-temperature high-shear viscosities, and soot dispersancy, while maintaining shear stability and oil solubility over a broad temperature range.
15. Lubricating Oil Composition with Calcium Borate and Magnesium Detergents and Poly(meth)acrylate Viscosity Index Improver
ENEOS CORP, 2023
Lubricating oil composition for internal combustion engines that improves fuel efficiency, LSPI suppression, oil consumption suppression, and detergency in a well-balanced manner. The composition contains a mineral or synthetic base oil with specific viscosity and evaporation properties. It also has calcium borate and magnesium detergents, a poly(meth)acrylate viscosity index improver, and optionally a molybdenum friction modifier.
16. Lubricating Oil Composition with Specific Viscosity Base Oil, Calcium and Magnesium Detergents, and Zinc Dialkyl Dithiophosphate
ENEOS CORP, 2023
A lubricating oil composition for internal combustion engines that balances fuel efficiency, low-speed pre-ignition (LSPI) suppression, lubricant consumption reduction, and detergency. The composition comprises a base oil with a specific viscosity range and evaporation loss, calcium and magnesium detergents, zinc dialkyl dithiophosphate, and an optional viscosity index improver. The calcium detergent is present in a specific concentration range to prevent LSPI, while the magnesium detergent maintains detergency. The zinc dialkyl dithiophosphate provides anti-wear protection.
17. Lubricating Composition with Comb Polymer Incorporating (Meth)Acrylate and (Meth)Acrylamide Monomers
TOTALENERGIES ONETECH, 2023
Lubricating compositions with improved cold thickening properties, comprising a specific comb polymer that enhances cold gelation performance, particularly in formulations with modified detergent chemistries. The polymer is derived from monomers with specific functional groups, including (meth)acrylates and (meth)acrylamides, and is used in amounts of 1-20% by mass in the lubricating composition.
18. Lubricating Oil Composition with Calcium-Containing Detergent and Silicon-Containing Compound
AFTON CHEMICAL CORP, 2023
Lubricating oil composition for reducing low-speed pre-ignition (LSPI) events in turbocharged gasoline direct-injection engines, comprising a base oil and an additive composition prepared by mixing a calcium-containing detergent and a silicon-containing compound. The composition provides a significant reduction in LSPI events while maintaining corrosion protection and storage stability.
19. Lubricating Oil Composition with Amine, Ether, and Ester Friction Modifiers and Molybdenum Dithiocarbamate
IDEMITSU KOSAN CO LTD, 2023
A lubricating oil composition for gasoline engines that achieves high fuel efficiency while maintaining low friction and wear characteristics across a wide temperature range. The composition contains a base oil, metal-based detergents, and a combination of amine-based, ether-based, and ester-based friction modifiers. The molybdenum dithiocarbamate content is optimized to balance friction reduction and base number retention. The composition exhibits improved fuel efficiency, reduced friction, and enhanced wear protection compared to conventional lubricating oils.
20. INFLUENCE OF LUBRICATING PROPERTIES OF MOTOR OILS ON THE RESOURCE OF THE ENGINE
Alimova Zebo Hamidullayevna, Ibrahimov Karimjon Ismailovich, Usmonov Zafar Tursunovich - The USA Journals, 2023
This article discusses the influence of lubricating properties of motor oils on the operation of engine parts. The quality of engine oils, especially lubricating indicators significantly affect the reliability of the engine, fuel consumption and other parameters. Therefore, high-quality selection and application of motor oils is very important.
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