Moisture-Resistant Organic-Inorganic Hybrid Transparent Solar Cells

A novel approach to improving perovskite solar cells through a novel electrode architecture that combines high efficiency with enhanced stability. The solution involves integrating PCBM, ZnO, or SnO2 into the perovskite layer, specifically through spin coating the perovskite solution onto the hole transport layer, followed by vacuum deposition and annealing. This integrated approach addresses the perovskite material's inherent limitations by incorporating a stable electrode component that prevents unwanted chemical reactions between the perovskite and metal electrodes.

Source

A perovskite solar cell structure and method that enables stable operation of perovskite solar cells through a novel encapsulation approach. The cell structure comprises a battery body with a base layer, a perovskite layer, and a tunneling interconnect layer, while the encapsulation film is a parylene composite layer. The encapsulation film is applied over the perovskite layer and serves as a barrier against environmental degradation, while maintaining optical transparency. The encapsulation film is specifically designed to accommodate the perovskite layer's unique properties and prevent water and oxygen-induced degradation.

Source

Perovskite solar cells with enhanced stability through a novel double-layer composite electrode structure. The cells employ a Cr/Bi metal electrode on the charge transport layer, followed by a perovskite absorption layer and a second charge transport layer. The electrode structure integrates a barrier layer between the metal electrode and charge transport layer, addressing the perovskite material's inherent sensitivity to environmental factors. This approach enables both high efficiency and long-term stability in perovskite solar cells.

Source

A stable and efficient perovskite solar cell with enhanced performance through a novel quasi-two-dimensional perovskite structure. The device incorporates a transparent substrate, conductive anode, hole transport layer, perovskite photosensitive layer, electron transport layer, and metal cathode arranged sequentially from bottom to top. The quasi-two-dimensional perovskite, comprising a fluorinated organic aromatic ammonium salt, is introduced to the perovskite photosensitive layer at a controlled concentration. This modification enables improved photovoltaic efficiency while addressing the stability challenges associated with traditional perovskite materials.

Source

High-performance perovskite solar cells produced through slot die coating using a functional additive containing hydroxyl and carboxyl functional groups. The additive enhances perovskite film quality by suppressing defects and improving charge carrier dynamics, while the slot die coating process enables uniform and stable perovskite layer formation. The method enables large-area perovskite solar cells with improved stability and durability compared to conventional spin-coating approaches.

Source

Flexible perovskite photovoltaic cells and electrical devices that enhance durability through optimized electrode design. The cells feature a substrate with integrated transparent conductive oxide (TCO) layers on both sides, with the light incident electrode on the transparent side. This configuration enables the formation of a single, continuous TCO layer across the entire cell surface, eliminating the need for separate electrodes and reducing sheet resistance. The transparent TCO layer also prevents cracks during bending, ensuring consistent performance across the cell's flexible architecture.

Source

A method for creating perovskite solar cells with enhanced stability through the controlled formation of one-dimensional perovskite layers. The method employs a novel three-layer approach where a lead-based perovskite layer is followed by a protective lead pyridine-2-carboxylate layer, and finally a third layer of lead pyridine-2-carboxylate. This multi-layer structure prevents ion migration and degradation through light, while maintaining optimal charge transport properties. The protective layer is specifically designed to prevent water and oxygen ingress, ensuring long-term device performance.

Source

A light-transmitting laminated perovskite solar cell and photovoltaic module that enhances visible light absorption while maintaining high efficiency. The cell architecture features symmetrically arranged perovskite absorption layers with charge transport layers on both sides, arranged between the electrodes. The perovskite absorption layers have absorption bands between 200-300 nm, and the charge transport layers are either electron or hole transport layers. The cell architecture incorporates a glass cover plate with a thickness that allows sequential stacking of the perovskite layers, with the width of the perovskite layer on the glass plate exceeding 2 microns. This design enables efficient light transmission while maintaining high solar conversion efficiency.

Source

Solar cells and photovoltaic systems that integrate photovoltaic generation and light emission capabilities through a single-layer perovskite material. The solar cell comprises a stacked transparent electrode, a second transparent electrode, and a perovskite layer between them. The perovskite layer absorbs sunlight and converts it into electrical energy, while the second transparent electrode serves as a light-transmissive window. This integrated architecture enables both power generation and light emission from a single-layer photovoltaic device.

Source

Trans perovskite solar cells with improved interface quality through a novel passivation layer. The solar cells feature a perovskite layer, hole transport layer, and passivation layer sequence, with the passivation layer comprising quinoxalinethiophene polymer. The passivation layer is prepared by spin coating a solution containing quinoxalinethiophene polymer or its derivatives on the hole transport layer, followed by spin coating a perovskite layer. This approach eliminates the issues of micro-hole defects and bubbles typically encountered in conventional perovskite solar cells.

Source

Perovskite solar cell with enhanced stability and efficiency through a novel nano-passivation layer design. The cell incorporates a nano-passivation layer at the perovskite-electrode interface, which extends to the charge transport layer. This layer prevents iodide ion diffusion into the metal electrode, suppresses moisture ingress, and protects the perovskite layer from degradation. The nano-passivation layer also inhibits the migration of metal ions from the electrode to the perovskite surface, thereby maintaining device stability.

Source

Trans-perovskite solar cells with enhanced stability and efficiency, achieved through the integration of a novel electron transport layer (ETL) that incorporates a specific molecular structure. The ETL, comprising an EGO-PEA material with a specific molecular structure, enables improved charge carrier transport and recombination kinetics in the perovskite layer, while maintaining device stability under environmental conditions. The ETL replaces conventional electron transport layers in perovskite solar cells, offering a more robust solution for addressing the stability limitations of perovskite photovoltaics.

Source

High-stability perovskite solar cells that prevent degradation through a novel electrode configuration. The cells feature a conductive base layer, hole transport layer, perovskite active layer, full-area electron transport layer, and a patterned non-metallic top electrode layer. The top electrode is achieved through magnetron sputtering of a patterned ITO layer, which prevents direct contact with the perovskite layer while ensuring complete separation of the interface. This configuration eliminates the common corrosion issues associated with metal electrodes in perovskite solar cells.

Source

A novel perovskite solar cell with enhanced stability through multifunctional additive engineering. The cell incorporates a perovskite light-absorbing layer containing 2-hydrazinobenzothiazole (2-HBT) as a doping agent, which improves humidity stability and prevents moisture-related degradation. The cell structure comprises a bottom electrode, hole transport layer, modification layer, perovskite light-absorbing layer, electron transport layer, buffer layer, and pair electrode. The 2-HBT doping level is controlled between 0.01-10wt% in the perovskite active layer. The cell's performance includes enhanced open-circuit voltage, short-circuit current density, fill factor, and photoelectric conversion efficiency compared to conventional perovskite solar cells.

Source

A Cu(acac)2-based perovskite photovoltaic cell with enhanced stability through interface passivation. The cell achieves improved efficiency by doping the perovskite layer with Cu(acac)2, which forms stable Cu2+ complexes with iodide ions in the photosensitive layer. These complexes passivate interface defects, particularly grain boundaries and grain boundaries, while maintaining high hole mobility. The Cu(acac)2 layer also prevents iodide degradation through reversible redox reactions, enabling continuous operation. The Cu(acac)2 layer is prepared through a novel spin-coating process that optimizes Cu2+ concentration and surface coverage. The cell's performance is demonstrated through enhanced stability and efficiency compared to conventional perovskite photovoltaic cells.

Source

High-stability perovskite solar cell with flexible architecture that enables efficient and durable photovoltaic applications. The cell features a perovskite absorption layer comprising FAPbI3, CsPbI3, or CsxFA1-xPbI3, which exhibits exceptional power conversion efficiency while maintaining stability under various environmental conditions. The cell's architecture incorporates a transparent conductive glass (TCO) electrode, which replaces traditional transparent conductive oxides (TCOs) and enables flexible integration into photovoltaic devices. This innovative approach enables the creation of flexible perovskite solar cells that can be integrated into wearable electronics, flexible displays, and photovoltaic building-integrated photovoltaics (BIPV) applications.

Source

Perovskite solar cell technology that addresses the safety and stability issues associated with conventional solar cells by separating the charge transport layers from the electrodes. The perovskite layer is isolated from the metal contacts, preventing direct contact and the associated leakage currents. This design enables the formation of separate charge transport layers, which are then connected to the electrodes, eliminating the path through the electrodes that can cause short circuits.

Source

A stable perovskite solar cell with enhanced energy conversion efficiency and long-term durability, achieved through the use of a novel hole transport layer material. The cell features a transparent conductive layer, electron transport layer, perovskite layer, hole transport layer, and metal electrode, with the hole transport layer comprising 4,4-didodecylthiophene-2,2'-bis-1,3-dithiocyclopentadiene dissolved in toluene and applied using a spin coating process. This material provides improved hole mobility and stability compared to conventional hole transport layers, enabling higher energy conversion efficiency and longer cell lifetimes.

Source

A high-efficiency and stable large-area translucent perovskite solar cell with enhanced performance through optimized interface layer preparation. The cell features a conductive substrate layer, a hole transport layer, an electron transport layer, and a seed layer, all of which are formed through controlled laser scribing and atomic layer deposition processes. The seed layer is specifically prepared by hydroxyl-modified zinc oxide crystals grown at low temperature, which enhances the interface between the perovskite layer and the substrate. This seed layer architecture enables uniform and free interfaces, leading to improved power conversion efficiency and stability. The cell also employs a transparent electrode made by magnetron sputtering of platinum and silver metal nanoarrays.

Source

A perovskite solar cell that achieves higher efficiency through a novel double-sided design. The cell incorporates a substrate, a first charge transport layer, a perovskite layer, a second charge transport layer, and a DMD electrode layer in sequence. The DMD electrode layer is formed through a sequential deposition process of metal and dielectric layers, with the dielectric layer comprising tin oxide, titanium oxide, zinc oxide, tungsten oxide, and silver oxide. This architecture enables both-side light reception while maintaining high transmittance and low resistance. The DMD electrode layer replaces traditional metal back electrodes, enabling improved photoelectric conversion efficiency.

Source