Hair coloring processes can cause significant structural damage to the hair shaft, with oxidative dyes raising the pH to 9-10 and breaking up to 85% of disulfide bonds in the cortex. Studies show that repeated coloring can reduce fiber tensile strength by 20-40% and increase surface roughness by 30-50% due to cuticle disruption.

The fundamental challenge lies in achieving desired color deposition and penetration while preserving the hair's natural protein structure, lipid content, and mechanical properties.

This page brings together solutions from recent research—including bond-protecting additives, pH-optimized dye systems, natural extract formulations, and sequential treatment approaches. These and other developments focus on maintaining hair integrity during the coloring process while delivering consistent, long-lasting color results.

1. Hair Dye Composition with Polyethyleneimine, Gallic Acid, and Phenylalanine-Copper Ion Complex

INDUSTRY-ACADEMIC COOPERATION FOUNDATION GYEONGSANG NATIONAL UNIVERSITY, 2024

A hair dye composition containing polyethyleneimine (PEI) and gallic acid that provides safe and minimal hair damage hair dyeing compared to traditional oxidative hair dyes. The composition contains an anionic surfactant, fatty acid, and vegetable oil to stabilize the dye. It also uses oxidizing agents like phenylalanine-copper ion complex instead of hydrogen peroxide. This composition avoids irritating alkaline agents and metal salts while having good color development.

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2. Hair Dye Composition with Low Surfactant Content and Specific Dye Concentration Range Containing Cationized and Water-Soluble Gelling Polymers

SAISHISEI CO LTD, 2023

Hair dye composition that provides stable dyeing properties, easy and even dyeing, and less damage to hair compared to conventional hair dyes. The composition contains one or more dyes selected from HC, basic, direct, and acidic dyes in a concentration range of 0.01-0.7% by weight. It also has a total active agent with a pure content of 12% or less, where the anionic surfactant content is 50% or less. The composition further contains a foaming agent, a cationized polymer, and a water-soluble gelling polymer as thickeners. The low surfactant content, specific dye concentration range, and thickener combination provide stable dyeing with less damage compared to conventional hair dyes.

3. Hair Dye Composition with Anionic Acylamino Acid and Nonionic Alkyl Glucoside Surfactants and pH Adjustment to Hair Isoelectric Point

NUMBER THREE KK, 2023

A hair dye and dyeing method that vividly colors hair without damaging it, regardless of the type of dye used. The hair dye contains specific surfactants and adjusts pH to match the hair's isoelectric point. This allows the dye to adhere to hair without charge, penetrate inside, and dye vividly without harming the cuticle. The surfactants are an anionic acylamino acid with a cocoyl group and a nonionic alkyl glucoside. The pH adjuster keeps the dye solution around the hair's isoelectric point.

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4. Method for Hair Dyeing with Additives Integrated into Dye Mixtures or Applied Sequentially

LIVING PROOF INC, 2023

Method for coloring hair that reduces damage and improves color retention by adding selected additives to hair dye mixtures or applying them before or after dyeing. The additives can be applied simultaneously with the hair dye, before dyeing, or after dyeing. The additives can be used at concentrations of 0.1-15% in the overall mixture. The additives can be antioxidants, amino acids, fatty acids, thiols, monomers, catalysts, or acidifiers. The additives can improve hair conditioning, reduce damage, enhance color consistency, and improve color resistance to washing.

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5. Oxidative Dye Composition with Low Coupler-to-Dye Intermediate Ratio for Hair Re-Lightening

SHISEIDO CO LTD, 2023

Reducing hair damage when re-lightening previously dyed hair by using a dedicated oxidative dye composition and de-dyeing composition. The oxidative dye composition has a low coupler-to-dye intermediate ratio compared to standard oxidative hair dyes. This allows better destaining with glyoxylic acid or derivatives when the hair is re-lightened. The low coupler ratio reduces hair damage compared to regular oxidative dyes. Using this specialized oxidative dye and de-dyeing kit can significantly reduce hair damage when re-lightening previously dyed hair.

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6. Composition with Isostearyl Silk, Tung Tree Seed Shell Extract, and Sacha Inchi Seed Oil in Specific Ratios

SUZHOU MAOER TECH CO LTD, 2023

A composition for both color-locking and hair care that prevents fading of hair dye and protects hair quality. The composition contains isostearyl silk, extract from tung tree seed shells and rapeseed, and Sacha Inchi seed oil. The specific ratios are 0.01-1:0.01-5:0.01-5 for isostearyl silk, tung oil, and Sacha Inchi oil, respectively. This combination provides color-locking to prevent dye fading and hair care benefits like protection against ultraviolet radiation.

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7. Natural Hair Dye Composition with pH-Adjusted Extracts from Black Beans, Ginseng Root, Perilla Leaf, Gomchi, and Chamomile

Lee Jeong-rye, LEE JUNG-RYE, 2022

A natural hair dye made from extracts of black beans, ginseng root, perilla leaf, gomchi, and chamomile. The dye is prepared by extracting these natural ingredients and adjusting the pH to 3-5 using an acidic mordant like alum. The extracts are mixed to make the hair dye composition, which avoids harsh chemicals and has lower irritation to the scalp compared to conventional synthetic hair dyes.

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8. Hair Dye Composition with Acid Dye, Chitosan, and Hair Treatment Agent

SONG HONG JONG, 2022

Hair dye composition and method that improves dyeability, reduces hair damage, and prevents color fading when dyeing hair with an acid dye. The composition contains an acid dye in a first agent along with a second agent that has a hair treatment and chitosan. Adding chitosan and hair treatment to the acid dye improves dye absorption into the hair, alleviates hair damage, and reduces color fading compared to using just the acid dye.

9. Sequential Hair Treatment Method Using Colorant or Bleaching Agent Followed by Amide and Alkylammonium Carboxylate Compounds

HERCULES LLC, HERCULES LLC, 2022

Method for dyeing or bleaching hair that enhances color intensity, reduces hair damage, and repairs damaged hair. The method involves applying two separate compositions to the hair in succession. The first composition contains a hair colorant or bleaching agent, and the second composition contains a hair treatment with amide and/or alkylammonium carboxylate compounds. This sequence of applications helps to improve color retention, minimize discoloration, and lessen hair damage compared to using just the first composition alone.

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10. Hair Lightening Composition with Antioxidants, Polycarboxylic Acids, and Amino Acids in Bleaching Agents

LOREAL, 2022

Hair lightening compositions that reduce damage to hair during bleaching by using specific antioxidants, polycarboxylic acids, and amino acids in combination with the bleaching agents. The compositions provide stable powders with built-in antioxidant and bonding properties that minimize damage and improve quality during hair lightening compared to traditional bleach formulations. The antioxidant, polycarboxylic acid, and amino acid system protects hair fiber integrity, reduces citric acid formation, and enhances sensory features like combability, softness, elasticity, moisture, and shine.

11. Hair Dye Shampoo Composition with Mixed Extract of Mulberry Fruit, Sangbaekpi, Upper Leaf, and Biotite

Kwang Dong Pharmaceutical Co., Ltd., KWANGDUK SINYOUK, 2022

A hair dye shampoo composition containing a mixed extract of mulberry fruit, sangbaekpi, upper leaf and biotite as an active ingredient. The composition provides hair coloring without damage to the scalp and hair. It also has improved scalp health after repeated use compared to conventional hair dyes. The dyeing effect is further enhanced with repeated use. The composition can dye hair without mixing separate oxidizing and color agents like traditional hair dyes. It provides stable hair coloring without fading and does not dye skin or nails like regular hair dyes. The composition can be used as a hair dye shampoo instead of regular shampoo for hair coloring.

12. Hair Dye Composition with Tannic Acid, Gallic Acid, and Divalent Iron Salt Forming Oxidizable Polyphenol Complexes

KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY, Korea Advanced Institute of Science and Technology, 2022

Composition for dyeing hair using a mixture of tannic acid, gallic acid, and a divalent iron salt like ferrous sulfate. The tannic acid and gallic acid are mixed in specific ratios to improve dyeability and color durability. The composition is applied to hair and oxidized by air to form black dye. The iron salt coordinates with the hydroxyl groups of the polyphenols to create insoluble complexes. When oxidized, these complexes dye the hair black. The kit contains the tannic acid-gallic acid mixture and iron salt pre-mixed.

13. Post-Treatment Composition with Levulinic Acid for Hair Dyeing with Buffered pH Range

CUTICULA CO LTD, 2021

Preventing hair damage from oxidative hair dye and suppressing fading of dyed hair by using a post-treatment agent containing levulinic acid with a pH of 4.0 to 6.0 after oxidative hair dyeing. The post-treatment agent is applied with the oxidative dye still on the hair, followed by rinsing with hot water. This method helps prevent hair damage from oxidative dyes and reduces fading of dyed hair. The levulinic acid helps buffer the pH near the hair's isoelectric point to prevent damage and suppress fading.

14. Hair Color Treatment Composition with Seed Oil, Biotin, Ceramide NP, Purple Chrysanthemum Extract, Grain-Derived Protein, Carrot Leaf Extract, and Red Ginseng Extract

ENHANCE B CO LTD, EnhanceV Inc., 2021

A hair color treatment composition containing natural ingredients like seed oil, biotin, ceramide NP, purple chrysanthemum extract, grain-derived protein, carrot leaf extract, and red ginseng extract. The composition provides hair coloring along with benefits like preventing hair damage, reducing hair thickness loss, and minimizing skin staining compared to commercial hair color products. The composition can also be used as a hair color shampoo.

15. Hair Fiber Reinforcement Method Using Cationic Surfactant and Polymeric Composition After Oxidative Treatment

UNILEVER IP HOLDINGS B V, 2021

Strengthening damaged hair fibers after oxidative treatments like bleaching to prevent brittleness and breakage. The method involves washing the bleached hair, followed by applying a specific composition containing cationic surfactants, fatty alcohols, and polymeric ingredients. The composition is applied to the hair, massaged in, and left for a few minutes before rinsing. This treatment helps rebuild and reinforce the hair fibers to counteract the damage caused by oxidative treatments.

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16. Hair Dye Composition with Natural Extracts and Dual-Agent System Containing Oxidation Dye and Alkalizing Agent

NATURAL KOREA CO LTD, Natural Korea, 2021

Hair dye composition that reduces irritation, hair damage, and odor compared to traditional oxidative hair dyes. The hair dye contains a first agent with an oxidation dye, alkalizing agent, and natural extract, and a second agent with an oxidizing agent. The natural extract contains compounds like selenium, Cordyceps fungus, Cudrania fruit extract, Eoseongcho (Houttuynia cordata thunb) extract, Hwangchil (Dendropanax morbifera Lev) leaf extract, raspberry extract, iris extract, avocado oil, and onion extract. The natural extract provides benefits like detoxification, hair regeneration, fragrance, antioxidant, and skin health.

17. Hair Coloring Method with Decoloring Pre-Treatment and Thioglycerol-Based Agent for Controlled pH Penetration

SUNNY PLACE CO LTD, 2021

A hair coloring method that uses a specific mix of products and steps to achieve better color retention, reduced skin irritation, and less damage to the hair compared to traditional hair dyes. The method involves decoloring the hair before applying a hair coloring agent and hair cosmetic in a specific ratio. This mixture is left on the hair for a certain time to open the cuticle, then a cuticle care agent is applied to tighten the cuticle and allow deeper dye penetration. The hair is heated during this step. The hair coloring agent contains thioglycerol, basic dyes, hydroxy, and other ingredients to raise the pH without alkaline agents. This allows deeper dye penetration into the cortex. The hair coloring agent pH is 3.5 or higher. The method also allows reducing the amount of basic dyes and HC dyes in the hair coloring agent

18. Hair Treatment Composition with Hydroxypropyl Gluconamide and Anionic Polymer

NAKANO SEIYAKU KK, 2020

Hair treatment agent that reduces hair damage while maintaining the performance of hair coloring, bleaching, permanent wave, and straightening agents. The agent contains hydroxypropyl gluconamide and an anionic polymer. The hydroxypropyl gluconamide suppresses hair damage and the anionic polymer improves coloring and perming. Using both components together provides a hair treatment agent that can be easily applied without complicated processes to reduce hair damage while maintaining color and perm performance.

19. Hair Dye Composition with Cationic Polymer and Gardenia Yellow Polymer

KNU INDUSTRY COOPERATION FOUND, 2020

Hair dye composition containing a cationic polymer and a polymer of gardenia yellow as an active ingredient. The composition provides improved hair dyeing with reduced damage to hair compared to traditional synthetic hair dyes. The cationic polymer helps the gardenia yellow pigment adhere better to damaged hair, increasing color intensity and wash fastness. It also improves hair permeability by allowing the pigment to penetrate deeper into the cortex rather than just coating the cuticle.

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20. Hair Dye Composition with Oxidizing Dye, Alkalinizing Agent, Natural Extract, and Complementary Oxidizing Agent

AHN YOUNGHEE, An Young-hee, 2020

Hair dye composition that prevents damage to hair by dyeing, shows excellent hair color effect, and reduces the occurrence of irritating odor. The composition includes a first agent comprising an oxidizing dye, an alkalinizing agent and a natural extract, and a second agent containing an oxidizing agent used in combination with the first agent.

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21. Hair Dye Composition with Bis(hydroxyethyl) Soy Amine Dioleate, Hydrolyzed Proteins, and Gentian Root Extract

ZHAOQING DICAI DAILY CHEMICAL SCIENCE AND TECH CO LTD, 2020

Hair dye composition containing natural ingredients that improves dyeing effectiveness while reducing irritation compared to traditional hair dyes. The composition includes bis(hydroxyethyl) soy amine dioleate, hydrolyzed wheat protein, hydrolyzed royal jelly protein, and gentian root extract. These natural components help the dye penetrate and deposit in hair better, providing more even and lasting color. The natural ingredients also reduce scalp irritation compared to synthetic dyes.

22. Pet Hair Dye Composition with Arginine, Aloe Vera, Ceramide, and Keratin for Enhanced Dye Penetration and Cortex Protection

JEON YEONG CHUN, 2019

Pet hair dye composition that reduces hair damage during dyeing and improves post-dye moisturization. The composition contains a first agent with an oxidizing dye and alkalizing agent, including arginine to improve dyeing speed. Additionally, the first agent can contain aloe vera gel, ceramide, and keratin extract to protect damaged hair. These additives open the hair cortex, enhance dye penetration, and reduce dyeing time. The second agent contains an oxidizing agent like hydrogen peroxide.

23. Hair Treatment Method Using Thiol and Sulfite Composition for Keratin Conversion and Basic Dye Penetration

LITTLE SCIENTIST KK, 2019

A hair treatment method that simultaneously dyes hair and repairs hair damage. The method involves treating hair with a composition containing a thiol compound and sulfite to convert keratin into a form that allows easy penetration of basic dyes. This is followed by treating the hair with a composition containing basic dyes. The conversion step improves dye uptake and uniformity while repairing hair damage caused by chemical treatments like oxidative dyes. Optional steps include reducing agents to further enhance penetration and oxidizing agents to stabilize the dye color.

24. Hair Dye Composition with Layered Tree Extract Prepared by Steaming and Solvent Extraction

CHODANG UNIV INDUSTRY ACADEMIC COOPERATION FOUNDATION, 2019

A composition for hair dyes containing a layered tree extract as an active ingredient to improve hair color retention, thickness, and damage. The composition can have 5-35% layered tree extract. The layered tree extract can be prepared by steaming and drying the bark or leaves of the tree, then extracting with water or alcohol at 30-50°C for 8-12 hours. This composition can be used in hair dyes, shampoos, and rinses to provide better hair color fastness, thickness, and damage reduction compared to conventional hair dyes.

25. Two-Part Hair Dye System with Aqueous Dye Precursors and Oleic Acid Component

CONOPCO INC, 2019

A two-part hair dye system that reduces damage during oxidative coloring. The system has an aqueous first part with hair dye precursors and a second part containing oleic acid. Mixing the two parts before application provides improved hair damage protection during the coloring process compared to using the dye precursors alone. The oleic acid in part two helps protect the hair from damage caused by the oxidative dye process.

26. Hair Dye Composition with Lamellar Liquid Crystal Structure Formed by Higher Alcohols, Fatty Acids, Nonionic Surfactants, and Polyol Esters

SEWHA P&C INC, 2018

Oxidation hair dye composition that provides improved dye retention, hair color persistence, and damage prevention compared to conventional hair dyes. The composition contains a specific mixture of higher alcohols (straight chain and branched), higher fatty acids, nonionic surfactants, and polyol esters. This mixture forms a lamellar liquid crystal structure that stabilizes the dye components and enhances penetration into hair. The composition is used in oxidative hair dyeing to improve dye retention, color vibrancy, and protect hair from damage during dyeing.

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27. Hair Dye Pretreatment Agent with Acyl Basic Amino Acid Derivative Compound

AJINOMOTO KK, 2018

A hair dyeing pretreatment agent and method to improve hair health and color retention after hair dyeing. The pretreatment agent contains an acyl basic amino acid derivative compound represented by formula (1) or salt thereof: [N+]-CH2-CO2-(CH2)n-CH(CH3)-CH2-CO2-(CH2)m-[O-] (1) where n and m are integers from 3 to 15. Applying this pretreatment agent before hair dyeing reduces hair damage, improves hair feel, and prevents dye outflow to enhance color retention.

28. Oxidative Hair Dye Composition with Dicarboxylic and Amino Acids for Keratin Fiber Protection

HENKEL AG & CO KGAA, 2017

Hair dye and bleaching agents that protect keratin fibers during oxidative coloring without weighing down the hair. The agents contain dicarboxylic acids like malic acid, tartaric acid, and fumaric acid. These acids help repair oxidative damage to the hair while coloring. The agents also contain amino acids like arginine and lysine. The dicarboxylic acids and amino acids protect the hair during oxidative dyeing by reducing damage compared to traditional agents.

29. Oxidative Hair Dye Composition with Natural Polysaccharides and Root Extracts

AMOREPACIFIC CORPORATION, Amorepacific Corporation, 2017

Hair dye composition for oxidative dyeing of keratin fibers like human hair that improves dyeability, color persistence, and reduces hair damage compared to conventional oxidative hair dyes. The dye composition contains natural ingredients like green tea polysaccharide, monosaccharide polysaccharide, peony root, licorice root, and carbohydrates as active ingredients. These natural components enhance dyeing, durability, and reduce hair damage when added to the oxidative hair dye formulation.

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30. Hair Treatment Composition with Saturated Dicarboxylic Acids and Amino Acids for Oxidative Coloring and Bleaching

HENKEL AG & CO KGAA, 2017

Hair-protecting agent and method for oxidative hair coloring and bleaching that reduces damage to keratin fibers during the process. The agent contains specific compounds like saturated dicarboxylic acids, amino acids, and alkalizing agents. The method involves applying an oxidative dye or bleach containing these compounds, then rinsing it out. The compounds protect the hair from oxidative damage during coloring/bleaching.

31. Hair Treatment Composition with Natural Ingredients for Integration with Reducing and Oxidizing Agents

KWON SOON KU, Kwon Soon-goo, 2017

Hair protection composition for permanent hair treatments that prevents damage to hair and scalp irritation caused by permanent chemicals. The composition contains natural ingredients like black beans, kelp, red beans, sorghum, and amino acids. Mixing this composition with the reducing agent used in permanent treatments minimizes hair breakage and loss of luster compared to using just the reducing agent alone. It also helps prevent scalp irritation. When used with the oxidizing agent in permanent treatments, it enhances hair gloss, elasticity, and nutrition.

32. Oxidative Dye Composition for Keratin Fibers with Natural Polysaccharides and Plant Extracts

Pacific Corporation, AMOREPACIFIC CORP, 2017

Composition for oxidative dyeing of keratin fibers like hair that contains natural substances to reduce scalp irritation, improve dyeing effect and color persistence, and minimize hair damage. The composition includes one or more natural substances selected from green tea polysaccharides, cypress polysaccharides, peony, lotus root, Eclipta prostrata, Bletilla striata, Sophora flavescens, and Coptis chinensis. The natural substances are added to oxidative hair dye compositions.

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33. Oxidative Hair Dye Composition with Plant Extracts and Surfactants

AMOREPACIFIC CORP, Amorepacific, 2016

A hair dye composition for oxidative dyeing containing natural ingredients to improve dyeing properties and color persistence while mitigating hair damage. The composition includes extracts from plants like Sophora flavescens and goldthread. It also contains surfactants, oils, preservatives, and ammonia for dyeing. The natural extracts enhance dyeability and color retention compared to traditional oxidative dyes.

34. Hair Dye Composition with Green Tea Polysaccharide, Cypress Polysaccharide, Peony, Lotus Root, and Eclipta Prostrata Extracts

AMOREPACIFIC CORP, Amorepacific, 2016

Natural ingredients for improving hair dye color and persistence while mitigating hair damage. The composition contains green tea polysaccharide, cypress polysaccharide, peony, lotus root, and Eclipta prostrata extracts. These natural ingredients enhance dyeability and color persistence when added to oxidative hair dyes.

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35. Oxidative Hair Dye Composition with Hyaluronic Acid-Infused First Agent and Oxidizing Second Agent

SHISEIDO COMPANY LTD, Shiseido Company, Limited, 2016

Oxidative hair dye composition that reduces hair damage and improves dyeing effectiveness while maintaining good hair moisture retention. The composition contains an oxidative hair dye with a first agent and a second agent containing an oxidizing agent. It also includes hyaluronic acid or a salt like B Cool in the first agent. Mixing hyaluronic acid in the dye before application enhances the dyeing effect and reduces hair damage compared to using just the dye. The hyaluronic acid concentration is preferably 0.0001-10% by weight.

36. Pretreatment Agent Comprising Quaternary Ammonium Salt, Liquid Higher Alcohol, and Higher Fatty Acid Alkali Salt Forming Aggregates

IKEDA BUSSAN CO LTD, 2015

Hair dye pretreatment agent to improve hair dyeing and conditioning effects. The pretreatment agent contains a quaternary ammonium salt, a liquid higher alcohol, and a higher fatty acid alkali salt. This mixture forms an aggregate that enhances hair dyeing and provides a better feel to the hair after dyeing. The quaternary ammonium salt improves dye absorption, the higher fatty acid alkali salt prevents damage, and the liquid higher alcohol conditions the hair.

37. Oxidative Hair Dye Formulation with Natural Polysaccharides and Plant Extracts

Amorepacific, AMOREPACIFIC CORP, 2015

A formulation for oxidative hair dyes that improves dyeability, color persistence, and reduces hair damage compared to traditional oxidative hair dyes. The formulation contains natural ingredients like green tea polysaccharide, cypress polysaccharide, peony, lotus root, and hanryeoncho. These natural components enhance dyeing properties, color longevity, and minimize hair damage after dyeing. They have affinity to hair and prevent color fading.

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38. Hair Dye Composition Incorporating Natural Saponins and Antioxidants

Amorepacific, AMOREPACIFIC CORP, 2015

A hair dye composition that improves dyeability, color persistence, and reduces hair damage compared to conventional hair dyes. The composition contains saponins from natural sources like dangsam, Ginseng, Salvia, Scrophulariaceae, and Sophora extract. Adding these saponins to the hair dye improves dye absorption, color longevity, and mitigates hair damage compared to dyes without saponins. The composition also contains antioxidants, reducing agents, and other standard hair dye ingredients.

39. Hair Dye Composition with PPD Substitutes, Natural Extracts, Bentonite Clay, Lecithin, and Ionic Mineral Complex

CHOI BOKYUNG, 2015

A hair dye composition that reduces scalp irritation, improves hair coating, and minimizes damage compared to conventional hair dyes. The composition contains p-phenylenediamine (PPD) substitutes like toluene-2,5-diamine sulfate, natural extracts like iris, licorice, gardenia, persimmon leaf, and bentonite clay, as well as lecithin and an ionic mineral complex. These ingredients calm the scalp during dyeing, improve hair coating, and reduce dye damage compared to traditional formulations with PPD.

40. Hair Care Compositions with Benzylidene Pentanedione Compounds for Free Radical Scavenging

SYTHEON LTD, 2015

Hair care compositions and methods that reduce hair damage from treatments like coloring, bleaching, perming, and shampooing. The compositions contain benzylidene pentanedione compounds like 2,6-dimethylbenzylidene-1,3-pentanedione. These compounds lessen hair damage when added to hair treatments or used as pretreatments/post-treatments. They can also be used in hair care products like conditioners to repair damage. The compounds scavenge free radicals generated during hair treatments to mitigate oxidative hair damage.

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