Tread Bonding Enhancement for Tire Manufacturing
64 patents in this list
Updated:
Tread separation failures in tires occur when adhesive bonds degrade under repeated stress cycles and environmental exposure. Field data shows that bond failures typically initiate at stress concentrations where adhesion strength falls below 40 N/mm, with degradation accelerated by thermal cycling between -20°C and 70°C during normal operation.
The fundamental challenge lies in maintaining robust chemical and mechanical bonding between dissimilar materials—rubber compounds and reinforcing elements—while withstanding dynamic loading and environmental stresses over the tire's service life.
This page brings together solutions from recent research—including surface modification techniques for improved wetting tension, novel adhesive compounds that eliminate toxic components, and engineered interfaces with enhanced chemical bonding through metal oxides and specialized vulcanization systems. These and other approaches focus on achieving durable bonds while meeting manufacturing and environmental requirements.
1. Non-Inflatable Rubber Wheel with Copper-Zinc Plated Metal Rim and Adhesive Layer for Integral Composite Formation
QINGDAO DOUBLESTAR TIRE IND CO LTD, QINGDAO DOUBLESTAR TIRE INDUSTRIAL CO LTD, QINGDAO HAILANG PREC INDUSTRY CO LTD, 2023
Non-inflatable rubber wheel that doesn't require air pressure for vehicle mobility. The wheel has a metal rim with raised protrusions, a bonding adhesive layer, and a tread rubber component. The metal rim is plated with copper-zinc. The adhesive layer is made of natural rubber, epoxidized natural rubber, styrene-vinyl styrene-butadiene rubber, carbon black, silica, silane, resorcinol formaldehyde resin, tackifying resin, cobalt salt, antioxidant, accelerator, insoluble sulfur, and hexamethoxymethyl amine. Vulcanizing the wheel forms an integral composite part. The raised protrusions on the rim increase contact area with the adhesive, and the copper-zinc plating provides chemical bonding. The adhesive layer
2. Rubber Composition with Metal Oxide for Enhanced Metal Adhesion
YOKOHAMA RUBBER CO LTD, YOKOHAMA RUBBER CO LTD:THE, 2023
Rubber composition for adhering metals, a rubber-metal composite material, and a tire using the same. The composition includes an oxide of a metal (excluding Al) having an ionization tendency between Mn and Mg to 100 parts by mass of diene rubber containing 80 parts by mass or more of natural rubber and/or synthetic isoprene rubber.
3. Rubber Composition with Diene and Plate Metal Oxide for Metal Adhesion
YOKOHAMA RUBBER CO LTD, YOKOHAMA RUBBER CO LTD:THE, 2023
Rubber composition for adhering metals, a rubber-metal composite material, and a tire using the same. The composition includes a diene rubber, a specific plate metal oxide in a specific amount, and a tire using the same.
4. Adhesive Composition with Polyurethane Prepolymer and Nanometer Oxide for Bonding Polyurethane Treads to Rubber Carcasses
SHANDONG HAOHUA TIRE CO LTD, 2023
High-strength adhesive for tire manufacturing that provides superior bonding between polyurethane tire treads and conventional rubber carcasses. The adhesive contains specific components like polyurethane prepolymer, plasticizer, silane coupling agent, filler, anti-aging agent, and nanometer oxide. This formulation enables strong and durable adhesion between the dissimilar rubber materials in composite tires. It improves tire integrity and longevity compared to conventional tire adhesives.
5. Rubber Compound with Silane Coupling Agent for Aramid Cord Bonding in Aviation Radial Tires
中国化工集团曙光橡胶工业研究设计院有限公司, CHINA NATIONAL CHEMICAL ENGINEERING GROUP SHUGUANG RUBBER INDUSTRY RESEARCH AND DESIGN INSTITUTE CO LTD, 2023
A rubber compound for bonding aramid cords in aviation radial tires to improve adhesion and prevent delamination during aging. The compound contains natural rubber, styrene-butadiene rubber, a silane coupling agent, fatty acid, anti-aging agents, anti-scorch agent, and insoluble sulfur. The silane coupling agent improves bonding between the rubber and aramid fibers. The fatty acid and anti-aging agents enhance durability. The compound allows better adhesion of the aramid cords in the tire belt to prevent separation and delamination during thermal cycling.
6. Polyisocyanate-Activated Textile Cord Bonding Method in Tire Manufacturing
Continental Reifen Deutschland GMBH, Kordsa Teknik Tekstil Anonim Sirketi, 2023
Producing a motor vehicle tire with improved bonding between textile cords and surrounding rubber to enhance tire durability. The method involves dipping the cords in a bath containing polyisocyanates to activate the bonding, instead of using resorcinol-formaldehyde dips. The cords are then coated with a rubber compound containing specific rubber types and carbon blacks. This avoids toxic and environmentally harmful resorcinol-formaldehyde dips while still providing adequate bonding.
7. Rubber-Steel Cord Composite Incorporating N,N-Dibenzylbenzothiazole-2-Sulfenamide and Bismaleimide Compound
Toyo Tire Corporation, 2023
Rubber-steel cord composite for tire belts and carcasses with improved adhesion to steel cords. The rubber composition contains a specific vulcanizing agent, N, N-dibenzylbenzothiazole-2-sulfenamide, and a bismaleimide compound.
8. Rubber-Steel Cord Composite with Specific Sulfur and Accelerator Ratios Excluding Cobalt Compounds
Toyo Tire Corporation, 2023
Rubber-steel cord composite for tire reinforcement with improved adhesion properties without using cobalt compounds. It contains a rubber composition with specific ratios of sulfur, N, N-dibenzylbenzothiazole-2-sulfenamide (accelerator), hexamethylene bis-thiosulfate disodium salt dihydrate and 1,6-bis(N, N-dibenzylthiocarbamoyldithio)hexane.
9. Steel Cords with Enhanced Surface Iron Content and Method of Fabrication via Electrolytic Brass Coating and Diamond Die Drawing
NV Bekaert SA, 2023
Steel cords for reinforcing rubber products like tires have improved adhesion to rubber and better aging resistance compared to traditional cords. The steel filament has an unusual amount of iron at the top surface. The iron content is higher than 4 atomic percent in a thin 3 nm layer below the surface. The iron-rich layer enhances adhesion to rubber while retaining good properties. The cord can be made by drawing wire with increased surface roughness using diamond dies, and electrolytically coating with brass.
10. All-Steel Radial Tire with Stacked Tread Layers and Specific Modulus Stress Ratio
贵州轮胎股份有限公司, GUIZHOU TYRE CO LTD, 2023
All-steel radial tire with interrelated constant elongation of upper and lower treads to maintain tire performance balance after tread improvements. The tire has a stacked upper tread layer A and lower tread layer B. The key is having a specific ratio of 100% modulus stress between the upper and lower tread layers: (0.7-0.8):1. This prevents breaking the tire's overall performance when improving tread performance by matching adjacent tread properties.
11. Sulfur-Cross-Linkable Rubber Mixture with Novolac and Etherified Melamine Resins for Adhesive Bonding to Strength Members
Continental Reifen Deutschland GmbH, 2023
Sulfur-cross-linkable rubber mixture for bonding rubber to strength members like textile or metallic cords in tires, belts, and hoses. The mixture contains novolac resins and etherified melamine resins to replace resorcinol as adhesive promoters for improved adhesion. The novolac resins are produced from a phenolic compound, aldehyde, and carbamate resin. The mixture also contains rubber, carbon black, silica, plasticizers, stabilizers, vulcanization activators, accelerators, and sulfur.
12. Pneumatic Tire Structure Incorporating Hydrogenated Copolymer with Triazine-Thiol Compound for Enhanced Rubber Adhesion
Toyo Tire Corporation, 2023
A pneumatic tire design that enables improved adhesion between a hydrogenated copolymer rubber and a diene rubber in a tire while maintaining the wear resistance of the hydrogenated rubber. The tire includes a rubber member A containing a hydrogenated copolymer, sulfur, and a triazine-thiol compound. Rubber member B contains sulfur and a diene rubber. The hydrogenated copolymer has a high molecular weight and high hydrogenation level. The triazine-thiol compound provides adhesion between the copolymer and diene rubber.
13. Method for Enhancing Adhesion in Non-Pneumatic Tires via Surface Modification and Vulcanizing Adhesive Application
TOYO TIRE CORP, 2023
Method to improve adhesion between the support structure and tread in non-pneumatic tires without using specialized resins. The method involves modifying the outer surface of the support structure in the radial direction to have wetting tension of 40-60 mN/m. This is achieved by surface treatments like corona or plasma treatment. Then a vulcanizing adhesive is applied to the modified surface and vulcanized to bond the support and tread. This ensures good adhesion without requiring resins with specific chemical structures or properties in the support structure.
14. Manufacturing Method for Non-Pneumatic Tires with Dual Adhesive Layer for Enhanced Structural Bonding
TOYO TIRE CORP, 2023
A method to manufacture non-pneumatic tires with improved adhesion between the support structure and tread without using resin-containing support structures. The method involves sequentially applying a first adhesive with higher affinity for the resin and a second vulcanizing adhesive to the support structure. This improves compatibility between the adhesives and the resin. The vulcanization bonds the support structure and tread to ensure adhesion without needing a resin-containing support.
15. Polybenzoxazine Adhesive Comprising Sulfide-Containing Benzoxazine Monomers for Metal-to-Rubber Bonding
COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, 2023
Polybenzoxazine adhesive for bonding metal to rubber that has improved thermal and chemical stability compared to conventional adhesives. The adhesive is made from a thermosetting polymer derived from benzoxazine monomers containing sulfide groups. The polymer can coat metal surfaces and bond to rubber for metal/rubber composites like vehicle tires. The adhesive has the same initial adhesion as conventional rubber/metal adhesives but with improved long-term performance due to its chemical stability.
16. Tread Rubber Composition with Syndiotactic 1,2-Polybutadiene and Fatigue Agent for Enhanced Durability
ZHONGCE RUBBER GROUP CO LTD, 2023
Tread rubber composition for high fatigue performance tires that improves tire durability by reducing cracking and wear over time. The rubber composition contains specific amounts of natural rubber, polybutadiene, filler, vulcanizing agents, activators, antioxidants, tear-resistant resins, and anti-fatigue agents. The rubber composition has a high content of syndiotactic 1,2-polybutadiene, which improves fatigue resistance. It also uses a fatigue agent to passivate crack growth and control microstructure factors like crosslink density and bond type distribution during vulcanization.
17. Tire with Thin Shoulder Tread and Fixation Layers for Enhanced Adhesion
Sumitomo Rubber Industries, Ltd., 2023
Tire design that reduces rolling resistance while ensuring wear resistance in limit run. The tire has a thin tread with reduced thickness in the shoulder region. To prevent separation of the thinner cap layer from the carcass in the shoulder, fixation layers are added between the cap layer and carcass. The fixation layers have higher adhesion than the cap layer to securely join the cap, base, and carcass. This prevents exposure of the more brittle base layer in the shoulder when contacting the road in limit run. The cap layer loss tangent is lower than the base layer to reduce rolling resistance.
18. Tire with Radial Carcass and Crown Reinforcement Featuring Low Thermal Conductivity Tread and Circumferential Reinforcing Elements
COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN & CIE, 2023
Tire design with improved durability and rolling resistance for heavy-duty applications like trucks and trailers. The tire has a radial carcass reinforcement covered by a crown reinforcement with circumferential reinforcing elements. The crown tread surface layer has low thermal conductivity polymer compound with diene elastomer matrix and inorganic fillers. This reduces heat buildup. The low thermal conductivity tread prevents excessive temperature rise in the tread from dissipating heat. The circumferential reinforcing elements compensate for this by limiting compression of the carcass reinforcement. This avoids fatigue of the carcass reinforcement. The circumferential reinforcing elements can be metal strips or cut metal sections. The low thermal conductivity tread and circumferential reinforcement improve tire durability without compromising rolling resistance.
19. Metallic and Resin Filament Twisted Cord with Inorganic Filler for Enhanced Elastomer Adhesion
BRIDGESTONE CORPORATION, 2023
Cord for reinforcing elastomers like rubber that has better adhesion to elastomers compared to conventional steel cords. The cord is made by twisting together metallic filaments with resin filaments. An inorganic filler is added to the resin filaments which improves adhesion to rubber during vulcanization.
20. Tire Tread Sipes with Rounded and Sharp Corner Geometry and Lamella Plate Manufacturing Method
NOKIAN RENKAAT OYJ, 2023
Tire with tread sipes for improved traction on wet and icy surfaces. The sipes have a unique shape with rounded corners at the bottom and sharp corners at the top. This shape allows the sipes to lock together when flexed, providing a better grip. A specific method of manufacturing a lamella plate to create the sipes with rounded and sharp corners is also disclosed. The plate is made from metal and material is added or removed to shape the corners. This design and manufacturing method improves tire performance and reduces manufacturing costs.
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Technological developments in tread bonding are still addressing important tire design issues, with an emphasis on enhancing performance, safety, and durability. Tire manufacturers are making tremendous progress toward producing safer and more dependable tires with cutting-edge techniques like improved rubber-steel cord adhesion, environmentally friendly bonding procedures, and novel material compositions.