Optimizing Inner Liner Extrusion in Tire Production

Low temperature fatigue resistant butyl rubber compositions with reduced glass transition temperatures. The compositions contain specific hydrocarbon resins having aromatic, olefinic, and aliphatic hydrogen contents in specific ranges, along with molecular weight and glass transition temperature ranges. These resins can be used in applications like tire inner liners to improve low temperature flexibility without increasing permeability.

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Pneumatic tire with improved air retention and reduced peeling between the innerliner and insulation. The tire has a carcass, insulation, and innerliner. The innerliner and insulation each contain a butyl rubber compound. The innerliner rubber has specific amounts of butyl rubber, carbon black, zinc oxide, and sulfur. The insulation rubber has specific amounts of butyl rubber, isoprene rubber, carbon black, and sulfur. The innerliner and insulation rubber compositions have predetermined ratios of butyl rubber content. This combination of high butyl rubber in the innerliner and specific ratios in the insulation improves adhesion between the two components, especially at the joint interface, to prevent peeling.

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Butyl rubber with improved processing and application properties for applications like tire inner liners, inner tubes, and curing bladders. The rubber contains isoprene conjugated diene units along with isobutylene units. This composition allows tailoring the molecular weight distribution to have higher proportions of high molecular weight components. This improves processing properties like green strength and elasticity while maintaining air tightness. The butyl rubber is prepared by copolymerizing isobutylene and isoprene using grafting agents, Lewis acids, and proton sources to control molecular weight and distribution.

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Tire innerliner composition and pneumatic tire that improves both air impermeability and fatigue resistance compared to conventional tire innerliners. The innerliner composition contains a butyl rubber and silicone oil with silicone having at least two mercapto groups. This composition allows better fatigue resistance without compromising air impermeability compared to traditional tire innerliners that use oil. The pneumatic tire uses this innerliner composition to improve both air retention and durability.

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Rubber composition for inner liners in tires that balances air barrier properties, moldability, and durability. The composition contains a rubber component and a terpene-based resin with a glass transition temperature (Tg) of 60°C or lower. This composition has an air barrier property index of 110 or higher, indicating low air permeability. The Tg terpene resin improves air barrier while the rubber component provides moldability. The low Tg resin prevents cracks compared to higher Tg resins. The composition is useful for tire inner liners and bladders that require air barrier properties and durability.

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Sealing compounds for tires with improved adhesion and cohesion properties for self-sealing tires. The compounds contain sealing gels made from diene rubbers crosslinked during polymerization. The gels have specific viscosities and molecular weight ranges. The compounds also have fillers like silica, carbon black, and clay. The sealing gels improve adhesion and cohesion compared to conventional sealants. The compounds are used as sealing layers in tire inner liners to prevent air leakage.

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Dispersant for improving dispersion of graphite or graphene nanofillers in elastomeric nanocomposites containing halobutyl rubber. The dispersant is made by reacting a halogenated copolymer derived from isobutylene and alkylstyrene with polycyclic aromatic hydrocarbons. This functionalized copolymer acts as a dispersant when added to halobutyl rubber nanocomposites containing graphite or graphene, leading to better exfoliation and dispersion of the nanofillers compared to unmodified halobutyl rubber. This improves the air barrier properties of the composites, making them suitable for tire innerliners.

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A thinner and lighter weight innerliner for pneumatic tires that provides improved oxygen and air permeability compared to conventional butyl rubber liners. The innerliner uses a blend of polyamide, α-olefin graft copolymer, and ionomer in the film layer. The film is treated with corona discharge to enhance adhesion. An amine and resorcinol-formaldehyde-latex (RFL) adhesive are applied to the treated film. This allows reducing the innerliner thickness significantly while maintaining air retention by eliminating the need for a separate low hysteresis rubber layer. The corona treatment and adhesive layers improve adhesion to the tire carcass.

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Improving adhesion between thermoplastic polyester resin films and rubber in applications like inner liners of tires by adding resorcin-based formaldehyde condensates to the resin and melamine-formaldehyde resins to the rubber. The condensate in the resin and the melamine-formaldehyde resin in the rubber bond during vulcanization molding to enhance adhesion.

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Tyre inner layer composition with improved airtightness compared to traditional butyl rubber liners. The composition contains diene elastomers, thermoplastic elastomers with polyisobutylene blocks, reinforcing filler, and a crosslinking system. The thermoplastic elastomers and filler are added in small amounts (1-99 phr) to the diene elastomers. This improves airtightness by reducing permeability without the need for high butyl rubber content. The lower permeability allows maintaining lower tyre inflation pressures for longer periods without air loss, improving tyre performance stability over time.

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A composition for manufacturing inner liners and inner tubes of tires with low air permeability and good flexibility. The composition contains an islands-in-the-sea structure where the continuous phase is a graphene oxide/rubber composition and the dispersed phase is epoxy natural rubber or thermoplastic resin. The graphene oxide/rubber composition is made by dispersing graphene oxide in rubber with ionic or covalent bonding between the graphene oxide and reactive rubber. This provides uniform graphene oxide dispersion, impermeable layers, and low air permeability. The solid rubber in the composition improves flexibility.

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Inner liner for pneumatic tires that adheres well to the rubber tire without needing an adhesive layer. The liner is a multilayer structure with a barrier layer containing a gas barrier resin, an elastomer layer, and an outermost layer containing an elastomer that adheres to diene rubber. This allows the liner to have good internal pressure retention and crack resistance without breaking or generating cracks due to tire deformation. The adhesion between the elastomer and rubber allows the liner to stick to the tire without separating during tire flexing.

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A method for manufacturing a pneumatic tire with a thin inner liner that prevents air leakage and eliminates the "air-in" phenomenon where small air bubbles form between the inner liner and tire components. The method involves using a thin polymer layer stack with specific layers for the inner liner. The stack has a styrene-isobutylene-styrene (SIBS) block copolymer outer layer with 0.05-0.6 mm thickness and an epoxidized styrene-butadiene-styrene (SEBS) block copolymer inner layer with 0.01-0.3 mm thickness. The tire is molded with this stack, vulcanized with pressure from a bladder, and then cooled immediately at 120°C or lower for 10-300 seconds without removing the mold. This solid

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Pneumatic tire with improved rolling resistance, ride comfort, and run flat durability. The tire uses a rubber composition for the sidewall and bead filler with low dynamic storage modulus (E') of 10 MPa or less at 25°C and 1% strain, and low total loss tangent (Σ) of 5.0 or less from 28 to 150°C. This rubber composition prevents sidewall deformation during run-flat operation while minimizing heat generation. The tire also uses a rubber composition for the inner liner with low air permeability. This prevents peeling of the sidewall from the inner liner while maintaining air retention.

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A tire manufacturing process that avoids issues like delamination, adhesion failure, corrosion, and steam penetration when curing tires in molds without bladders. The process involves forming a thin layer on the inner surface of a toroidal support that matches the tire shape. This layer, made of a crosslinkable elastomer, is cured before the tire is inserted. The layer prevents fluid penetration into the green tire during curing, preventing issues like delamination and adhesion failure. The layer can be impermeable to tire inflation air, acting as a liner to seal the tire. The layer material can be butyl rubber or diene elastomer.

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Tire innerliners with improved air barrier properties for preventing air and moisture permeation in tires. The innerliners contain a crosslinked elastomeric composition with specific ingredients like butyl rubber, reinforcing filler, and modified polycarboxylate. The composition can be used to make tire innerliners or liners in carcass plies. The compositions have better air barrier properties compared to conventional tire innerliners.

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Elastomeric compositions used in tire innerliners that have improved processability while maintaining air impermeability. The compositions are made by contacting elastomers with processing aids containing functionalized polymers having anhydride groups. The functionalized polymers improve processing properties like reduced viscosity and increased green tack without negatively impacting air barrier performance.

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Rubber composition for inner liners of tires that improves air retention, reduces hysteresis loss, and prevents crack growth while lowering heat generation compared to conventional liners. The composition contains specific ratios of butyl, natural/isoprene, and butadiene rubbers, along with mica filler with large aspect ratio and particle size.

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Rubber composition for tire inner liners that provides improved air retention and durability at low temperatures. The composition contains a rubber with glass transition temperature (-55°C or lower) like natural rubber or styrene-butadiene copolymer, and an organized lamellar clay mineral like swelling mica. This combination enables both reduced air permeation and better low temperature flexibility compared to traditional butyl rubber liners. The liners can be used in tires to prevent air leakage and maintain proper pressure at low temperatures.

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Self-supporting runflat tire with modified inner liner that improves performance and reduces cost compared to prior self-supporting tires. The tire has an inner liner that extends from shoulder to shoulder like a conventional tire, but also has an insert liner between the main liner and the tire carcass in the sidewall. This insert liner allows the main liner to be shorter since it doesn't need to extend all the way to the beads. The insert liner is made of the same material as the inner insert in the sidewall, which improves performance compared to using a single liner. The shorter main liner and insert liner together provide comparable performance to a full-length liner while reducing weight and cost. The insert liner also allows better air retention since the main liner doesn't extend into the sidewall where punctures can occur.

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