Silicon anodes offer theoretical capacities exceeding 3500 mAh/g—nearly ten times that of traditional graphite anodes—but experience volume changes of 300-400% during lithium insertion and extraction. This volumetric instability leads to particle pulverization, continuous solid-electrolyte interphase (SEI) formation, and electrical disconnection, resulting in rapid capacity fade within 50-100 cycles under standard testing conditions.

The fundamental challenge lies in developing silicon-based electrode architectures that can accommodate massive volume changes while maintaining electrical connectivity and interfacial stability throughout thousands of charge-discharge cycles.

This page brings together solutions from recent research—including silicon-carbon composites prepared through chemical vapor deposition, high-elasticity polymer matrices with controlled particle encapsulation, silicon alloys with specific compositions, and specialized polyimide binders achieving controlled porosity. These and other approaches provide practical pathways to harness silicon's high capacity while overcoming its inherent cycling stability limitations.

1. Secondary Battery with Silicon-Carbon Negative Electrode via Chemical Vapor Deposition in Porous Carbon Matrix

SUNWODA POWER TECHNOLOGY CO LTD, 2025

A secondary battery that enhances the performance and safety of lithium iron phosphate (LiFePO4) batteries through the integration of silicon-based negative electrodes. The battery comprises a silicon-carbon material prepared through controlled chemical vapor deposition, where silicon is deposited within the porous carbon matrix. This material enables improved thermal stability and structural integrity compared to conventional silicon electrodes, while maintaining the inherent benefits of LiFePO4. The battery's performance is evaluated through specific tests that assess both capacity retention and thermal management.

CN119786700A-patent-drawing

2. Lithium-Ion Battery with Silicon Oxide-Based Negative Electrode and Specialized Electrolyte Formulation

IONBLOX INC, AEON Blocks Co., Ltd., 2024

Lithium-ion battery with enhanced cycling performance through a novel negative electrode design that incorporates silicon oxide active materials without graphite. The design combines a high-capacity silicon oxide active material with a silicon-based negative electrode, featuring a polymer binder and conductive carbon additives. The electrolyte formulation employs a specific combination of lithium salts and solvents that provide superior stability and capacity retention. The battery achieves exceptional cycling performance, with capacities exceeding 800 cycles at a C-rate, while maintaining high energy density and power output.

CN112151788B-patent-drawing

3. Anode Active Material with High-Elasticity Polymer Matrix and Controlled Particle Size for Lithium-Ion Batteries

HONEYCOMB BATTERY CO, 2024

A high-elasticity polymer-protected anode active material for lithium-ion batteries that achieves enhanced cycle life and reversible capacity through controlled particle size engineering. The material comprises dispersed or encapsulated anode active particles in a high-elasticity polymer matrix or shell, with the polymer exhibiting recoverable tensile strain and lithium ion conductivity. The polymer matrix forms a continuous material phase that encapsulates the active particles, providing mechanical stability and preventing electrolyte contact. This novel material architecture enables high-rate operation, reversible capacity, and improved cycle life compared to conventional anode materials.

US12095079B2-patent-drawing

4. Silicon Alloy Negative Electrode Materials with Specific Compositions for Lithium-Ion Batteries

NINGDE AMPEREX TECHNOLOGY LTD, 2022

Silicon-based negative electrode materials for lithium-ion batteries that achieve high energy density while maintaining excellent cycling stability. The materials comprise silicon alloys with specific compositions, including ferrosilicon, silicon-aluminum, silicon-nickel, and ferro-silicon-aluminum. These alloys exhibit superior capacity retention and volumetric efficiency compared to conventional graphite-based materials, enabling higher energy density batteries. The alloys' unique properties, including enhanced surface reactivity and reduced SEI thickness, enable the development of negative electrodes with improved performance characteristics.

5. Negative Electrode Active Material Layer with Silicon-Based Particles and Polyimide Binder Achieving High Porosity

UBE INDUSTRIES, 2022

Active material layer for negative electrodes in lithium-ion batteries with improved cycle stability and capacity retention. The layer contains carbon particles and silicon-based particles that can occlude and release lithium ions, combined with a polyimide-based binder. The layer achieves a porosity of 42% or more, enabling both high capacity and excellent cycle characteristics. The binder is specifically optimized for this application, with controlled imide bond formation and molecular weight distribution.

KR20220075362A-patent-drawing

6. Silicon-Based Particle and Polyimide Binder Composite Layer for Lithium-Ion Battery Negative Electrodes

UBE INDUSTRIES LTD, 2022

Active material layer for negative electrodes in lithium-ion batteries that combines high charge/discharge capacity with excellent cycle characteristics. The layer contains silicon-based particles that can store and release lithium ions, combined with a polyimide-based binder with a porosity of less than 20%. This material structure enables both high capacity and cycle stability, while maintaining the conventional characteristics of negative electrodes.

KR20220073791A-patent-drawing

7. Aqueous Polymer Binder System with Additives for Silicon-Based Anode Fabrication

ENEVATE CORP, 2022

Aqueous-based polymer binder system for fabricating silicon-based anode materials that enables high-performance lithium-ion batteries while addressing the challenges of traditional anode materials. The binder system comprises a water-soluble polymer matrix with additives and modifiers that enhance its mechanical properties, thermal stability, and electrical conductivity. The system enables the fabrication of high-capacity silicon-based anode materials with improved cycle life, reduced capacity fade, and enhanced interfacial compatibility with the current collector.

US2022115651A1-patent-drawing

8. Lithium Ion Battery with Prelithiated Anode and Enhanced N/P Ratio

GENERAL AUTOMOBILE BALL SURROUNDING SCIENCE AND TECH OPERATION LIMITED RESPONSIBILITY CO, 2022

High performance lithium ion batteries with improved electrodes and methods of making them. The batteries have specific capacities, voltage windows, and cycle life improvements over conventional lithium ion batteries. The key innovation is prelithiating the negative electrode (anode) with excess lithium before cell assembly. This compensates for lithium loss during cycling and allows higher state of charge of the anode for specific energy gain. The prelithiated anode has a lithium occupancy fraction above 10%. The prelithiated anode and positive electrode have a N/P ratio above 1. This enables lower voltage operation below 5V. The prelithiation process involves adding lithium based on parameters like capacity, cycle efficiency, and initial charge level.

9. Polyimide Binder Comprising Tetrabutyl Titanate and Cyclodextrin with Aromatic Monomers for Silicon-Based Anodes

ZHEJIANG ZHONGKE JIUYUAN NEW MATERIAL CO LTD, 2021

Polyimide binder for lithium-ion batteries with improved cycle stability and energy density. The binder combines tetrabutyl titanate and cyclodextrin with aromatic ditincture monomers and diamines, forming a uniform slurry. The slurry is applied to silicon-based anode materials, coated onto current collector surfaces, and then cured through imidization. This binder system addresses the volume expansion issues of silicon-based anodes while maintaining excellent adhesion and performance.

CN113555552A-patent-drawing

10. Method for Preparing Lithium-Ion Battery Negative Electrodes with Cyclodextrin-Induced Pore Formation

HANGZHOU YIKANG NEW MAT CO LTD, 2020

A method for preparing lithium-ion battery negative electrode materials that addresses the safety issue of lithium dendrite formation during charging and discharging. The method involves incorporating cyclodextrin into the electrode preparation process, where cyclodextrin forms pores that create rich lithium ion binding sites while enhancing ion diffusion channels. This approach enables the material to maintain structural integrity and stability during repeated charge/discharge cycles, while still achieving high lithium ion storage capacity and rapid charging capabilities.

CN112018369A-patent-drawing

11. Pre-Lithiation of Silicon-Containing Battery Electrodes via Lithium Hydride Reaction

GM GLOBAL TECH OPERATIONS LLC, 2020

A method for pre-lithiating silicon-containing lithium-ion battery electrodes that enables high-capacity anodes with improved electrochemical performance compared to conventional materials. The method involves reacting lithium hydride with silicon-containing compounds to form pre-lithiated materials, which are then used to prepare electrode structures. The pre-lithiated materials contain silicon, lithium, and other elements, and can be formed through various methods including heating with inert gases and mechanical alloying. These pre-lithiated materials can be directly integrated into electrode structures to prepare negative electrodes for lithium-ion batteries, offering enhanced performance characteristics and reduced material costs.

12. Lithium-Ion Battery Electrodes with Localized Pyrolyzed Polymer Matrix and Silicon-Infused Carbon Gradient

GM GLOBAL TECHNOLOGY OPERATIONS LLC, 2020

High-performance lithium-ion battery electrodes that achieve superior performance through localized pyrolysis of polymer matrices. The electrodes combine a conductive current collector with a pyrolyzed carbon matrix containing silicon, which enables controlled expansion and contraction during lithium insertion/extraction. The pyrolysis process creates a gradient in the polymer matrix composition, allowing precise control over the material properties. This approach eliminates the conventional interface damage associated with traditional electrode fabrication methods, resulting in enhanced electrochemical performance and reduced capacity fade.

US2020220154A1-patent-drawing

13. SiO/C/Cu Composite Material with Hydrothermal Synthesis and Copper Layer Deposition for Lithium-Ion Batteries

HEFEI GUOXUAN HIGH TECH POWER ENERGY CO LTD, 2019

A novel SiO/C/Cu composite material for lithium-ion batteries that addresses the challenges of silicon anode degradation through improved conductivity, structural stability, and cycle performance. The material is prepared through a novel hydrothermal synthesis process followed by Cu layer deposition, resulting in a SiO/C/Cu composite with enhanced electrical conductivity, structural integrity, and reversible lithium insertion properties. This composite material enables high-capacity, long-cycle performance in lithium-ion batteries while maintaining superior cycle life compared to conventional silicon anodes.

CN110635129A-patent-drawing

14. Lithium-Ion Battery with Silicon Anode and Controlled Partial Lithiation

WACKER CHEMIE AG, 2018

Lithium-ion batteries with enhanced anode performance through controlled partial lithiation. The battery comprises a cathode, an anode comprising silicon particles, a separator, and an electrolyte. The anode material in the fully charged battery is only partly lithiated, with the maximum lithium uptake capacity corresponding to 4.4 lithium atoms per silicon atom. This partial lithiation maintains reversible capacity while preventing significant volume expansion during charging and discharging. The battery achieves stable capacity retention through the formation of stable solid electrolyte interfaces (SEIs) and controlled passivation layers.

15. Lithium-Ion Battery with Silicon-Based Negative Electrode and Defined Voltage Window for Volume Expansion Control

GM GLOBAL TECHNOLOGY OPERATIONS LLC, 2017

Improving the life cycle of lithium-ion batteries containing silicon-based negative electrodes through controlled charging/discharging conditions. The battery comprises a positive electrode, a lithium-silicon negative electrode with at least 10% silicon content, a separator between the positive and negative electrodes, and an electrolyte. The battery operates within a specific voltage window (0.7-0.07V) to prevent excessive volume expansion and contraction during charging/discharging, thereby maintaining structural integrity and preventing degradation of the negative electrode active material.

16. Carbon-Silicon Composite Material with Amorphous Carbon Core and Pyrolytic Carbon Matrix

SHENZHEN BTR NEW ENERGY MAT INC, 2017

Carbon-silicon composite material for lithium-ion batteries with enhanced performance. The composite comprises a core of amorphous carbon and a pyrolytic carbon layer, where the amorphous carbon is dispersed within the pyrolytic carbon matrix. The composite is prepared through a fusion coating process where the amorphous carbon is incorporated into the pyrolytic carbon matrix. The composite exhibits superior capacity retention and cycle performance compared to conventional graphite-based anodes, with specific capacities above 400 mAh/g and excellent charge/discharge characteristics.

CN106784741A-patent-drawing

17. Core-Shell Silicon-Carbon Composite Material with Single-Step Fabrication via Chemical Vapor Deposition

ZHONGTIAN ENERGY STORAGE TECHNOLOGY CO LTD, 2016

A core-shell structure silicon-carbon composite material and its preparation method for lithium-ion batteries, enabling high energy density and safety through a novel core-shell architecture. The material consists of a silicon-carbon core encapsulated by a carbon shell, which is prepared through a single-step process involving a silicon-carbon slurry, graphite substrate, and chemical vapor deposition. This approach eliminates the complex steps and equipment required in conventional methods while maintaining superior cycle performance and electrical conductivity.

18. Silicon Particle Negative Electrode with Polymer-Coated Surface Layer for Enhanced Cycle Durability

SHINETSU CHEMICAL CO, 2016

Negative electrode material for lithium-ion batteries that enhances cycle life through improved surface properties. The material comprises silicon particles with a surface layer containing a thin organic polymer coating, which enhances adhesion and resistance to water. The polymer layer also improves electron and ion conductivity, while maintaining stability during charging and discharging. This material enables lithium-ion batteries with superior cycle life compared to conventional silicon-based electrodes.

19. Lithium-Ion Battery Electrolyte with Sulfone-Boron Trifluoride Complex and Cyclic Ester Compound

CONTEMPORARY AMPEREX TECHNOLOGY CO LTD, 2016

Lithium-ion battery electrolyte comprising an organic solvent, an electrolyte and an additive comprising a sulfone - boron trifluoride complex compound and a cyclic ester compound containing a sulfur oxygen double bond, for improving cycling performance and safety of lithium-ion batteries.

CN105895957A-patent-drawing

20. SiOx-Graphite-Amorphous Carbon Composite Anode with Controlled Particle Size and Composition

INSTITUTE OF CHEMISTRY, CHINESE ACADEMY OF SCIENCES, 2016

SiOx-based composite anode materials for high-energy density lithium-ion batteries, comprising a combination of amorphous carbon, graphite, and SiOx, with optimized composition and particle size. The composite achieves superior cycle stability and high specific capacity (4200mAh/g) through precise control of SiOx content and particle size, while maintaining excellent conductivity and interface stability.

Get Full Report

Access our comprehensive collection of 23 documents related to this technology

Identify Key Areas of Innovation in 2025